Sensitized luminescence from lanthanides in d-f bimetallic complexes

doi:10.1016/j.ccr.2009.12.028

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	Sensitized luminescence from lanthanides in d-f bimetallic complexes
	Chen, Fang-Fang; Chen, Zhu-Qi; Bian, Zu-Qiang; Huang, Chun-Hui
刊名	COORDINATION CHEMISTRY REVIEWS
	2010-05-01
卷号	254 期号:9-10 页码:991-1010
关键词	Bimetallic Complexes Transition Metals Lanthanides Red Emission Nir Emission
ISSN号	0010-8545
DOI	10.1016/j.ccr.2009.12.028
英文摘要	This article reviews progress in the research of transition metal-lanthanide (d-f) bimetallic complexes Through efficient energy transfer, sensitized luminescence of lanthanide ions from the visible range (Eu(III)) to the near-infrared region (Nd(III), Yb(III), Er(III) and Pr(III)) is obtained in these bimetallic assembles The d-block in d-f bimetallic complexes mainly contributes to the improvement of lanthanide emission efficiency and the extension of the excitation window for the lanthanide complexes. Examples are catalogued by various transition metals, such as Ru(II), Os(II) (Fe(II)), Pt(II) (Au(I)), Pd(II), Cr(III), Co(III), Zn(II) and Ir(III). The relevant synthetic procedures, crystal structures and photophysical properties of these d-f complexes are briefly described Additionally, the molecular properties responsible for the performance of certain d-f systems, such as energy levels, nuclear distances and coordination environments, will be discussed (C) 2009 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000276380800005
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/70455]
专题	中国科学院化学研究所
通讯作者	Huang, Chun-Hui
作者单位	Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,et al. Sensitized luminescence from lanthanides in d-f bimetallic complexes[J]. COORDINATION CHEMISTRY REVIEWS,2010,254(9-10):991-1010.
APA	Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,&Huang, Chun-Hui.(2010).Sensitized luminescence from lanthanides in d-f bimetallic complexes.COORDINATION CHEMISTRY REVIEWS,254(9-10),991-1010.
MLA	Chen, Fang-Fang,et al."Sensitized luminescence from lanthanides in d-f bimetallic complexes".COORDINATION CHEMISTRY REVIEWS 254.9-10(2010):991-1010.