Lanthanide Complexes Coordinated by a Dianionic Bis(amidinate) Ligand with a Rigid Naphthalene Linker

doi:10.1002/ejic.201000330

CORC > 化学研究所 > 中国科学院化学研究所

	Lanthanide Complexes Coordinated by a Dianionic Bis(amidinate) Ligand with a Rigid Naphthalene Linker
	Yakovenko, Marina V.1; Cherkasov, Anton V.1; Fukin, Georgy K.1; Cui, Dongmei 2; Trifonov, Alexander A.1
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2010-07-01
期号	21 页码:3290-3298
关键词	Lanthanides Amidinates Coordination Modes Ligand Design
ISSN号	1434-1948
DOI	10.1002/ejic.201000330
英文摘要	The synthetic pathway to a new bis(amidine) ligand with a conformationally rigid naphthalene linker, 1,8-C(10)H(6)[NHC-(tBu)=N(2,6-Me(2)-C(6)H(3))][N=C(tBu)NH(2,6-Me(2)-C(6)H(3))] (3) was elaborated. Deprotonation of this bis(amidine) ligand with two equivalents of nBuLi and subsequent reaction with anhydrous LnCl(3) (Ln = Y, Nd, Sm) allowed the synthesis of the chlorido complexes [1,8-C(10)H(6){NC(tBu)N-2,6-Me(2)C(6)H(3)}(2)]YCl(dme) (4), [1,8-C(10)H(6){NC(tBu)N-2,6-Me(2)C6H(3)}(2)]Nd(dme)(mu-Cl)(2)Li(dme) (5), and [1,8-C(10)H(6){NC(tBu)-N-2,6-Me(2)-C(6)H(3)}(2)]Sm(thf)(mu-Cl)(2)Li(thf)(2) (6), which are coordinated by the linked dianionic bis(amidinate) ligand. The structures of complexes 4-6 were established by X-ray diffraction studies, which reveal that the new ligand framework can coordinate to the lanthanide atoms in different fashions depending on the central atom ion size. Alkylation of complex 6 with equimolar amounts of LiCH(2)SiMe(3) afforded the unexpected amido-amidinate complex [{1,8-C(10)H(6)(NC(tBu)-N-2,6-Me(2)-C(6)H(3))(2)}{1,8-C(10)H(6)(NC(tBu)N-2,6-Me(2)-C(6)H(3))-(NH)}Sm][Li(dme)(3)] (7), which obviously results from the cleavage of one amidinate group during decomposition of the transient alkyl species and ligand redistribution.
语种	英语
出版者	WILEY-BLACKWELL
WOS记录号	WOS:000280654000007
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/69339]
专题	中国科学院化学研究所
通讯作者	Trifonov, Alexander A.
作者单位	1.Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603600, Russia 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Yakovenko, Marina V.,Cherkasov, Anton V.,Fukin, Georgy K.,et al. Lanthanide Complexes Coordinated by a Dianionic Bis(amidinate) Ligand with a Rigid Naphthalene Linker[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2010(21):3290-3298.
APA	Yakovenko, Marina V.,Cherkasov, Anton V.,Fukin, Georgy K.,Cui, Dongmei,&Trifonov, Alexander A..(2010).Lanthanide Complexes Coordinated by a Dianionic Bis(amidinate) Ligand with a Rigid Naphthalene Linker.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(21),3290-3298.
MLA	Yakovenko, Marina V.,et al."Lanthanide Complexes Coordinated by a Dianionic Bis(amidinate) Ligand with a Rigid Naphthalene Linker".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .21(2010):3290-3298.