Synthesis, crystal structures and properties of a series of three-dimensional lanthanide coordination polymers with the rigid and flexible mixed dicarboxylate ligands of 1,4-benzene dicarboxylic acid and succinic acid

doi:10.1016/j.molstruc.2008.12.057

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	Synthesis, crystal structures and properties of a series of three-dimensional lanthanide coordination polymers with the rigid and flexible mixed dicarboxylate ligands of 1,4-benzene dicarboxylic acid and succinic acid
	Wang, Chun-Guang 1; Xing, Yong-Heng 1; Li, Zhang-Peng 1; Li, Jing 1; Zeng, Xiao-Qing 2; Ge, Mao-Fa 2; Niu, Shu-Yun 1
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2009-03-17
卷号	921 期号:1-3 页码:126-131
关键词	Lanthanide Coordination Polymer Succinic Acid Synthesis Crystal Structure Photoluminescent Property 1 4-benzene Dicarboxylic Acid
ISSN号	0022-2860
DOI	10.1016/j.molstruc.2008.12.057
英文摘要	A series of new lanthanide coordination polymers, with the formula [Ln(Suc)(0.5)(p-BDC)] (Ln = Eu (1), Sm (2), Tb (3), Pr (4), Ho (5); H(2)SuC = succinic acid; p-H2BDC = 1,4-benzene dicarboxylic acid), have been synthesized under hydrothermal condition and all of them have been structurally characterized. X-ray diffraction analyses reveal that complexes 1-5 are isostructural and crystallized in orthorhombic space group Pbca. One-dimensional infinite inorganic edge-sharing polyhedra chains formed by lanthanide ions and tetradentate carboxyl groups of succinic acid ligands, link to each other through the carbon atoms of succinic acid ligands and phenyl groups of the 1,4-benzene dicarboxylic acid ligands, to lead to a three-dimensional framework structure. in addition, the phase purities of the bulk samples were identified by X-ray powder diffraction. The photoluminescent properties of I and 3 were discussed in detail. (c) 2008 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000264711100019
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/67531]
专题	中国科学院化学研究所
通讯作者	Xing, Yong-Heng
作者单位	1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Chun-Guang,Xing, Yong-Heng,Li, Zhang-Peng,et al. Synthesis, crystal structures and properties of a series of three-dimensional lanthanide coordination polymers with the rigid and flexible mixed dicarboxylate ligands of 1,4-benzene dicarboxylic acid and succinic acid[J]. JOURNAL OF MOLECULAR STRUCTURE,2009,921(1-3):126-131.
APA	Wang, Chun-Guang.,Xing, Yong-Heng.,Li, Zhang-Peng.,Li, Jing.,Zeng, Xiao-Qing.,...&Niu, Shu-Yun.(2009).Synthesis, crystal structures and properties of a series of three-dimensional lanthanide coordination polymers with the rigid and flexible mixed dicarboxylate ligands of 1,4-benzene dicarboxylic acid and succinic acid.JOURNAL OF MOLECULAR STRUCTURE,921(1-3),126-131.
MLA	Wang, Chun-Guang,et al."Synthesis, crystal structures and properties of a series of three-dimensional lanthanide coordination polymers with the rigid and flexible mixed dicarboxylate ligands of 1,4-benzene dicarboxylic acid and succinic acid".JOURNAL OF MOLECULAR STRUCTURE 921.1-3(2009):126-131.