Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands

doi:10.1016/j.ica.2009.01.010

CORC > 化学研究所 > 中国科学院化学研究所

	Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands
	Liu, Min; Yang, Zhipei; Sun, Wenhao; Li, Xiuping; Li, Juan; Ma, Jinshi; Yang, Guoqiang
刊名	INORGANICA CHIMICA ACTA
	2009-06-01
卷号	362 期号:8 页码:2884-2889
关键词	Metal-organic Frameworks Hydrothermal Synthesis Multiple Building Blocks Crystal Structures Zinc Coordination Polymers
ISSN号	0020-1693
DOI	10.1016/j.ica.2009.01.010
英文摘要	Two novel metal-organic frameworks [Zn(3)(BTC)(2)(bbi)(3)](n) (1) (H(3)BTC = 1,3,5-benzenetricarboxylate, bbi = 1,1'-(1,4-butanediyl)bis(imidazole)) and{[Zn(3)(BTC)(2)(bix)(3) center dot 2.5H(2)O]}(n) (2) (bix = 1,4-bis(imidazole-1-ylmethyl) benzene) have been hydrothermally prepared and characterized. Analysis of the structure of 1 displays a 3D framework exhibiting a threefold interpenetration net of identical Zn(1.5)(BTC)(bbi)(1.5) single frameworks. In the structure of 2, BTC(3-) and bix build up infinite tubes extending to a 3D non-interpenetrated porous framework. Moderate fluorescent emissions in the solid state at room temperature were observed in both the compounds. (C) 2009 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000265509200054
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/66805]
专题	中国科学院化学研究所
通讯作者	Yang, Guoqiang
作者单位	Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Liu, Min,Yang, Zhipei,Sun, Wenhao,et al. Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands[J]. INORGANICA CHIMICA ACTA,2009,362(8):2884-2889.
APA	Liu, Min.,Yang, Zhipei.,Sun, Wenhao.,Li, Xiuping.,Li, Juan.,...&Yang, Guoqiang.(2009).Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands.INORGANICA CHIMICA ACTA,362(8),2884-2889.
MLA	Liu, Min,et al."Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands".INORGANICA CHIMICA ACTA 362.8(2009):2884-2889.