Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension | |
Chen, Huhe1; Guo, Zhengduo1; Yu, Fangting1; Qi, Jian1; Zhang, Li1; Zhou, Yong2; Yang, Zhanlan1; Xu, Yizhuang1; Wu, Jinguang1; Xu, Guangxian1 | |
刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE |
2008-12-01 | |
卷号 | 328期号:1页码:158-165 |
关键词 | Mixed Micelle Vesicle Structural Transition |
ISSN号 | 0021-9797 |
DOI | 10.1016/j.jcis.2008.09.011 |
英文摘要 | In this study, the influence of La3+ on the mixed egg-yolk phosphatidylcholine (EYPC)-sodium taurocholate TC) aggregates was investigated by using turbidity, quasi-elastic light-scattering (QELS) technique, Fourier transform infrared (FTIR) spectroscopy, and transmission electron microscopy (TEM). La3+ ions exert different effects on different EYPC-TC aggregates. The EYPC-TC mixed spheroidal micelles are stable in the presence of La3+ ions. The EYPC-TC vesicles are aggregated by the interaction of La3+ with the EYPC phosphate group. Particularly, La3+ causes structural transition of the EYPC-TC mixed disk micelles by changing the colloidal properties of TC. This process includes two steps, destruction of mixed disk micelles and formation of mixed spheroidal micelle. Several intermediate structures such as multi-lamellar vesicles and cylindrical micelles were observed during the transition. The experimental data and analysis in the current study suggest that metal ion is one of the important factors to control the structure of the EYPC-TC self-assemblies. And the possible influence of metal ions on the properties of bile biocolloid has been discussed. (C) 2008 Elsevier Inc. All rights reserved. |
语种 | 英语 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
WOS记录号 | WOS:000261042800023 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/65121] |
专题 | 中国科学院化学研究所 |
通讯作者 | Yang, Zhanlan |
作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Chinese Acad Sci, State Key Lab Polymer Phys, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Huhe,Guo, Zhengduo,Yu, Fangting,et al. Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2008,328(1):158-165. |
APA | Chen, Huhe.,Guo, Zhengduo.,Yu, Fangting.,Qi, Jian.,Zhang, Li.,...&Xu, Guangxian.(2008).Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension.JOURNAL OF COLLOID AND INTERFACE SCIENCE,328(1),158-165. |
MLA | Chen, Huhe,et al."Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension".JOURNAL OF COLLOID AND INTERFACE SCIENCE 328.1(2008):158-165. |
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