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Preparation and surface properties of acrylic copolymers containing fluorinated monomers
Tai-jiang Gui; Hao Wei; Ying Zhao; Xiu-lin Wang; Du-jin Wang; Duan-fu Xu
刊名CHINESE JOURNAL OF POLYMER SCIENCE
2006-11-01
卷号24期号:6页码:575-578
关键词Acrylate Copolymers Fluorinated Monomers Surface Property Contact Angle X-ray Energy Dispersive Analysis
ISSN号0256-7679
英文摘要A series of copolymers comprising butylmethacrylate, styrene, butylacrylate, hydroxypropyl acrylate and perfluoroalkyl methacrylate were synthesized by the free radical polymerization using BPO as an initiator. The surface property of the copolymer films was subsequently characterized. The contact angle measurements and energy dispersive analysis of X-ray (EDAX) show that the length and content of perfluoroalkyl side chains in the copolymers are crucial for the preparation of the film with low surface energy. At a given content of fluorinated monomers in the copolymers, the longer the perfluoroalkyl side chain, the larger the water contact angle of the copolymer films will be. On the other hand, the higher the content of fluorinated monomers, the lower the surface energy is. The water contact angle increases with the increase of the fluorinated monomer content and reaches,a plateau at 3 wt% of fluorinated monomer content.
语种英语
出版者WORLD SCIENTIFIC PUBL CO PTE LTD
WOS记录号WOS:000242005500004
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/58007]  
专题中国科学院化学研究所
通讯作者Du-jin Wang
作者单位1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
2.Ocean Univ China, Chem & Chem Engn Coll, Qingdao 266003, Peoples R China
3.Marine Res Inst Chem Ind, Qingdao 266071, Peoples R China
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GB/T 7714
Tai-jiang Gui,Hao Wei,Ying Zhao,et al. Preparation and surface properties of acrylic copolymers containing fluorinated monomers[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2006,24(6):575-578.
APA Tai-jiang Gui,Hao Wei,Ying Zhao,Xiu-lin Wang,Du-jin Wang,&Duan-fu Xu.(2006).Preparation and surface properties of acrylic copolymers containing fluorinated monomers.CHINESE JOURNAL OF POLYMER SCIENCE,24(6),575-578.
MLA Tai-jiang Gui,et al."Preparation and surface properties of acrylic copolymers containing fluorinated monomers".CHINESE JOURNAL OF POLYMER SCIENCE 24.6(2006):575-578.
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