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Separation of azeotropic mixture by a biopolymer, chitin
Chen, LY; Zhang, JC; Wang, N; Huang, MY; Jiang, YY
刊名REACTIVE & FUNCTIONAL POLYMERS
2005
卷号62期号:3页码:249-259
关键词Azeotropic Mixtures Azeotrope Chitin Separating Column Separating Agent Biopolymer
ISSN号1381-5148
DOI10.1016/j.reactfunctpolym.2004.10.004
英文摘要The azeotropic mixture cannot be separated by the general distillation method. A biopolymer, chitin, packed into the straight glass column has been found to be able to separate various kinds of azeotropic mixtures at room temperature and under 1 atm. The azeotropic mixtures such as cyclohexane-butanol, acetone-methanol, cyclohexane-acetone, ethyl acetate-methanol, benzene-ethanol, toluene-methanol etc., can be separated to obtain 100% pure main compound respectively in high separation efficiency. The separation efficiency could be affected by the magnitude of chitin particle, length and diameter of the column, components of azeotropic mixture, weight ratio of two components in the azeotropic mixture and velocity of adding mixture to column. When suitable separation conditions were selected, the separation efficiency could be amounted to over 90%. Another important advantage is that this separating agent, chitin, can be reused without remarkable change in efficiency for the separation of azeotropic mixture. © 2005 Elsevier B.V. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000228890800003
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/57613]  
专题中国科学院化学研究所
通讯作者Chen, LY
作者单位Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Chen, LY,Zhang, JC,Wang, N,et al. Separation of azeotropic mixture by a biopolymer, chitin[J]. REACTIVE & FUNCTIONAL POLYMERS,2005,62(3):249-259.
APA Chen, LY,Zhang, JC,Wang, N,Huang, MY,&Jiang, YY.(2005).Separation of azeotropic mixture by a biopolymer, chitin.REACTIVE & FUNCTIONAL POLYMERS,62(3),249-259.
MLA Chen, LY,et al."Separation of azeotropic mixture by a biopolymer, chitin".REACTIVE & FUNCTIONAL POLYMERS 62.3(2005):249-259.
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