Dyads and triads containing perylenetetracarboxylic diimide and porphyrin: Efficient photoinduced electron transfer elicited via both excited singlet states

doi:10.1021/jp045163e

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	Dyads and triads containing perylenetetracarboxylic diimide and porphyrin: Efficient photoinduced electron transfer elicited via both excited singlet states
	Xiao, SQ ; El-Khouly, ME ; Li, YL ; Gan, ZH ; Liu, HB ; Jiang, L ; Araki, Y ; Ito, O ; Zhu, D
刊名	JOURNAL OF PHYSICAL CHEMISTRY B
	2005-03-03
卷号	109 期号:8 页码:3658-3667
ISSN号	1520-6106
DOI	10.1021/jp045163e
英文摘要	Synthesis, characterizations, and photophysical properties of new photoactive dyads and triads containing perylenetetracarboxylic diimide (PIm) and porphyrin (free-base porphyrin (H2P) and zinc porphyrin (ZnP)), in which both entities were connected with a short ether bond, were examined with the aim of using these systems for molecular photonics. The porphyrin(P)-PIm systems absorbed strongly across the visible region, which greatly matched the solar spectrum. The geometric and electronic structures of the dyads and triads were probed using density function theory method at the B3LYP/3-21G level. It was revealed that the majority of the highest-occupied molecular orbital was located on the porphyrin entity, while the lowest-unoccupied molecular orbitals were entirely on the PIm entity. The excited-state electron-transfer processes were monitored by both steady-state and time-resolved emission as well as transient-absorption techniques in polar solvent benzonitrile. Upon excitation of the P (H2P and ZnP) moieties, efficient fluorescence quenching of the P moiety was observed, suggesting that the main quenching paths involved charge separation from the excited singlet porphyrin (P-1) to the PIm moiety. Upon excitation of the PIm moiety, fluorescence quenching of the (1)PIm moiety was also observed. The nanosecond transience of spectra in near-IR region revealed the charge separation process from the P moieties to the PIm moiety via their excited singlet states. The lifetimes of the charge-separated states were evaluated to be 7-14 ns, depending on the solvent polarity. Photosensitized electron mediation systems were also revealed in the presence of methyl viologen and sacrificial electron donor.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000227247100080
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/56991]
专题	中国科学院化学研究所
通讯作者	Ito, O
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
推荐引用方式 GB/T 7714	Xiao, SQ,El-Khouly, ME,Li, YL,et al. Dyads and triads containing perylenetetracarboxylic diimide and porphyrin: Efficient photoinduced electron transfer elicited via both excited singlet states[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2005,109(8):3658-3667.
APA	Xiao, SQ.,El-Khouly, ME.,Li, YL.,Gan, ZH.,Liu, HB.,...&Zhu, D.(2005).Dyads and triads containing perylenetetracarboxylic diimide and porphyrin: Efficient photoinduced electron transfer elicited via both excited singlet states.JOURNAL OF PHYSICAL CHEMISTRY B,109(8),3658-3667.
MLA	Xiao, SQ,et al."Dyads and triads containing perylenetetracarboxylic diimide and porphyrin: Efficient photoinduced electron transfer elicited via both excited singlet states".JOURNAL OF PHYSICAL CHEMISTRY B 109.8(2005):3658-3667.