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Heat transport enhancement of thermal energy storage material using graphene/ceramic composites
Zhou, Mi1,2,3; Bi, Hui1; Lin, Tianquan1; Lu, Xujie4; Wan, Dongyun1; Huang, Fuqiang1,2,3; Lin, Jianhua2,3
刊名CARBON
2014-08-01
卷号75页码:314-321
ISSN号0008-6223
DOI10.1016/j.carbon.2014.04.009
英文摘要Graphene/ceramic composites are proposed by directly depositing graphene on the insulating Al2O3 particles by chemical vapor deposition without any metal catalysts. Carbothermic reduction occurring at the Al2O3 surface is vital during the initial stage of graphene nucleation and the graphene sheet can connect with neighboring sheets to completely cover Al2O3 particles. The quality and layer number of graphene on Al2O3 can be finely tailored by changing the growth temperature and gas ratio. Graphene coated Al2O3 (G-Al2O3) composites are used as effective fillers of stearic acid (SA) to increase the thermal transport property. By the optimization of the layer number of graphene, size of Al2O3 particles and ratio of G-Al2O3/SA in a quantitative, their thermal conductivities significantly increase up to 11 folds from 0.15 to 1.65W m(-1) K-1. The great improvement is attributed to the high thermal transfer performance of graphene and excellent wettability between graphene and SA. When the G-Al2O3/SA composites with the graphene coated porous Al2O3 foam, the thermal conductivity further reaches to 2.39 W m(-1) K-1, and the corresponding latent heat is 38 J g(-1). It demonstrates the potential applications of graphene in thermal transport and thermal energy storage devices. (C) 2014 Elsevier Ltd. All rights reserved.
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000336877600032
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/52915]  
专题中国科学院化学研究所
通讯作者Huang, Fuqiang
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
3.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
4.Univ Nevada, High Pressure Sci & Engn Ctr HiPSEC, Las Vegas, NV 89154 USA
推荐引用方式
GB/T 7714
Zhou, Mi,Bi, Hui,Lin, Tianquan,et al. Heat transport enhancement of thermal energy storage material using graphene/ceramic composites[J]. CARBON,2014,75:314-321.
APA Zhou, Mi.,Bi, Hui.,Lin, Tianquan.,Lu, Xujie.,Wan, Dongyun.,...&Lin, Jianhua.(2014).Heat transport enhancement of thermal energy storage material using graphene/ceramic composites.CARBON,75,314-321.
MLA Zhou, Mi,et al."Heat transport enhancement of thermal energy storage material using graphene/ceramic composites".CARBON 75(2014):314-321.
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