Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion

doi:10.1002/ejoc.201402105

CORC > 化学研究所 > 中国科学院化学研究所

	Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion
	Wang, Xi 1,2; Zhou, Yujing 1,2; Ji, Guojing 1,2,3; Wu, Guojiao 1,2; Li, Ming 3; Zhang, Yan 1,2; Wang, Jianbo 1,2
刊名	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
	2014-05-01
卷号	2014 期号:15 页码:3093-3096
关键词	Diazo Compounds Carbenes Fluorine Migratory Insertion
ISSN号	1434-193X
DOI	10.1002/ejoc.201402105
英文摘要	A strategy to introduce the SCF3 group through the Cu-I-promoted reaction of diazo compounds with the nucleophilic AgSCF3 trifluoromethylthiolation reagent was developed. Various diazo compounds were smoothly converted under mild conditions to form the C(sp(3))-SCF3 bond. Mechanistically, migratory insertion of SCF3-bearing Cu carbene intermediates is involved in this transformation.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000336377000007
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52511]
专题	中国科学院化学研究所
通讯作者	Wang, Jianbo
作者单位	1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
推荐引用方式 GB/T 7714	Wang, Xi,Zhou, Yujing,Ji, Guojing,et al. Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014,2014(15):3093-3096.
APA	Wang, Xi.,Zhou, Yujing.,Ji, Guojing.,Wu, Guojiao.,Li, Ming.,...&Wang, Jianbo.(2014).Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014(15),3093-3096.
MLA	Wang, Xi,et al."Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 2014.15(2014):3093-3096.