Ionic liquid modified montmorillonite-supported Ru nanoparticles: highly efficient heterogeneous catalysts for the hydrodeoxygenation of phenolic compounds to cycloalkanes

doi:10.1039/c4cy00250d

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	Ionic liquid modified montmorillonite-supported Ru nanoparticles: highly efficient heterogeneous catalysts for the hydrodeoxygenation of phenolic compounds to cycloalkanes
	Xu, Huanjun; Wang, Kongchen; Zhang, Hongye; Hao, Leiduan; Xu, Jilei; Liu, Zhimin
刊名	CATALYSIS SCIENCE & TECHNOLOGY
	2014
卷号	4 期号:8 页码:2658-2663
ISSN号	2044-4753
DOI	10.1039/c4cy00250d
英文摘要	The Ru/MMT@IL-SO3H catalyst was prepared by immobilizing Ru nanoparticles onto montmorillonite (MMT) with the assistance of an acidic ionic liquid (1-sulfobutyl-3-methylimidazolium hydrosulfate, IL-SO3H). Transmission electron microscopy examination indicated that the loaded Ru species were distributed uniformly on the MMT support with a particle size of about 1.3 nm, which existed mainly in the form of a metallic state as confirmed by X-ray photoelectron spectroscopy analysis. X-Ray diffraction analysis indicated that the interlayer distance of MMT was increased due to the impregnation of IL-SO3H. The activity of Ru/MMT@IL-SO3H for hydrodeoxygenation (HDO) of various phenolic compounds was investigated. It was demonstrated that the as-prepared catalyst served as a bifunctional catalyst and displayed high efficiency for HDO reactions of a series of phenolic compounds to cycloalkanes.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000339551400049
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/51457]
专题	中国科学院化学研究所
通讯作者	Xu, Huanjun
作者单位	Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Xu, Huanjun,Wang, Kongchen,Zhang, Hongye,et al. Ionic liquid modified montmorillonite-supported Ru nanoparticles: highly efficient heterogeneous catalysts for the hydrodeoxygenation of phenolic compounds to cycloalkanes[J]. CATALYSIS SCIENCE & TECHNOLOGY,2014,4(8):2658-2663.
APA	Xu, Huanjun,Wang, Kongchen,Zhang, Hongye,Hao, Leiduan,Xu, Jilei,&Liu, Zhimin.(2014).Ionic liquid modified montmorillonite-supported Ru nanoparticles: highly efficient heterogeneous catalysts for the hydrodeoxygenation of phenolic compounds to cycloalkanes.CATALYSIS SCIENCE & TECHNOLOGY,4(8),2658-2663.
MLA	Xu, Huanjun,et al."Ionic liquid modified montmorillonite-supported Ru nanoparticles: highly efficient heterogeneous catalysts for the hydrodeoxygenation of phenolic compounds to cycloalkanes".CATALYSIS SCIENCE & TECHNOLOGY 4.8(2014):2658-2663.