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Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl
Ma, Zhishuang; Zhang, Hongye; Yang, Zhenzhen; Zhang, Yanfei; Yu, Bo; Liu, Zhimin
刊名JOURNAL OF MATERIALS CHEMISTRY A
2014
卷号2期号:45页码:19324-19329
ISSN号2050-7488
DOI10.1039/c4ta03829k
英文摘要Highly mesoporous carbons (MCs) were prepared by the carbonization of biomass sources, including glucose, cellulose, and lignin, with eutectic salt (KCl/ZnCl2, denoted as PZ) as the porogen agent and catalyst. The influences of the mass ratio of carbon sources to PZ, the heating program, and the calcination temperature on the textural structures of the carbons were investigated. It was demonstrated that the MC derived from glucose with a mass ratio of glucose to PZ of 1 : 6 exhibited a specific surface area (SSA) of 1297 m(2) g(-1) and a pore volume of 2.727 cm(3) g(-1) dominated with a mesopore volume proportion of 92.2% and that the MCs from cellulose and lignin also showed relatively high mesoporous proportions in the range of 63.2-87.5% and SSAs higher than 1000 m(2) g(-1). Furthermore, based on the TGA, FT-IR and N-2 sorption analyses, the generation of a high proportion of mesopores in MCs was also studied.
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000344384000027
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/51153]  
专题中国科学院化学研究所
通讯作者Liu, Zhimin
作者单位Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Ma, Zhishuang,Zhang, Hongye,Yang, Zhenzhen,et al. Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(45):19324-19329.
APA Ma, Zhishuang,Zhang, Hongye,Yang, Zhenzhen,Zhang, Yanfei,Yu, Bo,&Liu, Zhimin.(2014).Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl.JOURNAL OF MATERIALS CHEMISTRY A,2(45),19324-19329.
MLA Ma, Zhishuang,et al."Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl".JOURNAL OF MATERIALS CHEMISTRY A 2.45(2014):19324-19329.
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