Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl | |
Ma, Zhishuang; Zhang, Hongye; Yang, Zhenzhen; Zhang, Yanfei; Yu, Bo; Liu, Zhimin | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A |
2014 | |
卷号 | 2期号:45页码:19324-19329 |
ISSN号 | 2050-7488 |
DOI | 10.1039/c4ta03829k |
英文摘要 | Highly mesoporous carbons (MCs) were prepared by the carbonization of biomass sources, including glucose, cellulose, and lignin, with eutectic salt (KCl/ZnCl2, denoted as PZ) as the porogen agent and catalyst. The influences of the mass ratio of carbon sources to PZ, the heating program, and the calcination temperature on the textural structures of the carbons were investigated. It was demonstrated that the MC derived from glucose with a mass ratio of glucose to PZ of 1 : 6 exhibited a specific surface area (SSA) of 1297 m(2) g(-1) and a pore volume of 2.727 cm(3) g(-1) dominated with a mesopore volume proportion of 92.2% and that the MCs from cellulose and lignin also showed relatively high mesoporous proportions in the range of 63.2-87.5% and SSAs higher than 1000 m(2) g(-1). Furthermore, based on the TGA, FT-IR and N-2 sorption analyses, the generation of a high proportion of mesopores in MCs was also studied. |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000344384000027 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/51153] |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Zhimin |
作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Zhishuang,Zhang, Hongye,Yang, Zhenzhen,et al. Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(45):19324-19329. |
APA | Ma, Zhishuang,Zhang, Hongye,Yang, Zhenzhen,Zhang, Yanfei,Yu, Bo,&Liu, Zhimin.(2014).Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl.JOURNAL OF MATERIALS CHEMISTRY A,2(45),19324-19329. |
MLA | Ma, Zhishuang,et al."Highly mesoporous carbons derived from biomass feedstocks templated with eutectic salt ZnCl2/KCl".JOURNAL OF MATERIALS CHEMISTRY A 2.45(2014):19324-19329. |
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