Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation

doi:10.1002/anie.201309650

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	Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation
	Hu, Fangdong 1,2,3; Xia, Ying 1,2; Ye, Fei 1,2; Liu, Zhenxing 1,2; Ma, Chen 1,2,3; Zhang, Yan 1,2; Wang, Jianbo 1,2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2014-01-27
卷号	53 期号:5 页码:1364-1367
关键词	C-h Activation Diazo Compounds Homogeneous Catalysis Metal-carbene Complexes Migratory Insertion
ISSN号	1433-7851
DOI	10.1002/anie.201309650
英文摘要	A coupling reaction of N-phenoxyacetamides with N-tosylhydrazones or diazoesters through Rh-III-catalyzed C-H activation is reported. In this reaction, ortho-alkenyl phenols were obtained in good yields and with excellent regio- and stereoselectivity. Rh-carbene migratory insertion is proposed as the key step in the reaction mechanism.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000336504500031
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/50233]
专题	中国科学院化学研究所
通讯作者	Wang, Jianbo
作者单位	1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China 3.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
推荐引用方式 GB/T 7714	Hu, Fangdong,Xia, Ying,Ye, Fei,et al. Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(5):1364-1367.
APA	Hu, Fangdong.,Xia, Ying.,Ye, Fei.,Liu, Zhenxing.,Ma, Chen.,...&Wang, Jianbo.(2014).Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(5),1364-1367.
MLA	Hu, Fangdong,et al."Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.5(2014):1364-1367.