Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source

doi:10.1351/PAC-CON-11-06-09

CORC > 化学研究所 > 中国科学院化学研究所

	Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source
	Liang, Shuguang; Liu, Huizhen; Liu, Jinli; Wang, Weitao; Jiang, Tao; Zhang, Zhaofu; Han, Buxing
刊名	PURE AND APPLIED CHEMISTRY
	2012
卷号	84 期号:3 页码:779-788
关键词	Cu/zno/al2o3 Heterogeneous Catalysis Hydrogenation Lauryl Alcohol Methanol Methyl Laurate Supercritical Fluids
ISSN号	0033-4545
DOI	10.1351/PAC-CON-11-06-09
英文摘要	Hydrogenation of methyl laurate was conducted over a Cu/ZnO/Al2O3 catalyst, using methanol as the solvent and hydrogen source, to give lauryl alcohol. In this process, the solvent underwent partial decomposition in contact with the catalyst to generate hydrogen, which served as the hydrogenation agent. The effect of different factors on the reaction was examined, to optimize production of lauryl alcohol with high conversion efficiency and selectivity. Use of methanol as the solvent not only favored the reaction, but also suppressed a side reaction involving transesterification between methyl laurate and lauryl alcohol. Under optimal reaction conditions, 91.8 % conversion of methyl laurate and 88.8 % yield of lauryl alcohol could be achieved.
语种	英语
出版者	INT UNION PURE APPLIED CHEMISTRY
WOS记录号	WOS:000301282100027
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/48977]
专题	中国科学院化学研究所
通讯作者	Jiang, Tao
作者单位	Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Liang, Shuguang,Liu, Huizhen,Liu, Jinli,et al. Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source[J]. PURE AND APPLIED CHEMISTRY,2012,84(3):779-788.
APA	Liang, Shuguang.,Liu, Huizhen.,Liu, Jinli.,Wang, Weitao.,Jiang, Tao.,...&Han, Buxing.(2012).Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source.PURE AND APPLIED CHEMISTRY,84(3),779-788.
MLA	Liang, Shuguang,et al."Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source".PURE AND APPLIED CHEMISTRY 84.3(2012):779-788.