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A robust fuel cell cathode catalyst assembled with nitrogen-doped carbon nanohorn and platinum nanoclusters
Zhang, Linwei1,2; Zheng, Ning1; Gao, Ang1; Zhu, Chunmei1; Wang, Zhiyong1; Wang, Yuan1; Shi, Zujin1; Liu, Yan1
刊名JOURNAL OF POWER SOURCES
2012-12-15
卷号220页码:449-454
关键词Catalytic Cathode Durability Nitrogen-doped Oxygen Reduction Reaction Polymer Electrolyte Membrane Fuel Cells
ISSN号0378-7753
DOI10.1016/j.jpowsour.2012.08.009
英文摘要A highly durable and active nanocomposite cathode catalyst (Pt/NSWCNH) is assembled with "unprotected" Pt nanoclusters and nitrogen-doped single-wall carbon nanohorns (NSWCNH) as building blocks by a convenient process. The specific catalytic activity and mass catalytic activity for the oxygen reduction reaction over Pt/NSWCNH is 1.60 and 1.75 times as high as those over a commercial Pt/C catalyst, respectively. There is no obvious loss in the catalytic activity of Pt/NSWCNH after potential cycling from 0.6 to 1.1 V versus RHE for 15,000 cycles at 30 degrees C, under the oxidizing conditions for the electrochemically catalytic reduction of O-2. TEM characterization results reveal that, during the accelerated aging tests, Pt nanoparticles in Pt/NSWCNH are more stable than that in Pt/C-JM, showing a low increase in the particle size. (C) 2012 Elsevier B.V. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000309990300060
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/48897]  
专题中国科学院化学研究所
通讯作者Wang, Yuan
作者单位1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Linwei,Zheng, Ning,Gao, Ang,et al. A robust fuel cell cathode catalyst assembled with nitrogen-doped carbon nanohorn and platinum nanoclusters[J]. JOURNAL OF POWER SOURCES,2012,220:449-454.
APA Zhang, Linwei.,Zheng, Ning.,Gao, Ang.,Zhu, Chunmei.,Wang, Zhiyong.,...&Liu, Yan.(2012).A robust fuel cell cathode catalyst assembled with nitrogen-doped carbon nanohorn and platinum nanoclusters.JOURNAL OF POWER SOURCES,220,449-454.
MLA Zhang, Linwei,et al."A robust fuel cell cathode catalyst assembled with nitrogen-doped carbon nanohorn and platinum nanoclusters".JOURNAL OF POWER SOURCES 220(2012):449-454.
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