Hydrogen-bonding induced change of crystallization behavior of poly(butylene succinate) in its mixtures with bisphenol A

doi:10.1007/s10118-013-1364-y

CORC > 化学研究所 > 中国科学院化学研究所

	Hydrogen-bonding induced change of crystallization behavior of poly(butylene succinate) in its mixtures with bisphenol A
	Luo, Fa-liang 1,2,3; Luo, Fa-hai 1,2; Xing, Qian 3; Zhang, Xiu-qin 3; Jiao, Hong-qiao 4; Yao, Min 4; Luo, Chun-tao 4; Wang, Du-jin 3
刊名	CHINESE JOURNAL OF POLYMER SCIENCE
	2013-12-01
卷号	31 期号:12 页码:1685-1696
关键词	Poly(Butylene Succinate) Bisphenol a Hydrogen Bonding Crystallization Behavior
ISSN号	0256-7679
DOI	10.1007/s10118-013-1364-y
英文摘要	In the present work, the blend of poly(butylene succinate) (PBS) and bisphenol A (BPA) was prepared by solution mixing, and the intermolecular interactions between the two components were characterized by a combination of nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR). The results showed that intermolecular hydrogen-bonding forms between the carbonyl group of PBS and phenol hydroxyl of BPA. With the increase of BPA content, more hydrogen bonds were formed. The effect of hydrogen bonding on the crystallization behavior of PBS was investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The results showed that the overall isothermal crystallization kinetics and the spherulite growth rate of PBS decrease with the increase of BPA content, while the PBS spherulite size increases with BPA content.
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000326884900008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/46635]
专题	中国科学院化学研究所
通讯作者	Luo, Fa-liang
作者单位	1.Ningxia Univ, Key Lab Energy Resource & Chem Engn Ningxia, Yinchuan 750021, Peoples R China 2.Liupanshan High Sch Ningxia, Yinchuan 750002, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China 4.Shenhua Ningxia Coal Ind Grp, Yinchuan 750011, Peoples R China
推荐引用方式 GB/T 7714	Luo, Fa-liang,Luo, Fa-hai,Xing, Qian,et al. Hydrogen-bonding induced change of crystallization behavior of poly(butylene succinate) in its mixtures with bisphenol A[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2013,31(12):1685-1696.
APA	Luo, Fa-liang.,Luo, Fa-hai.,Xing, Qian.,Zhang, Xiu-qin.,Jiao, Hong-qiao.,...&Wang, Du-jin.(2013).Hydrogen-bonding induced change of crystallization behavior of poly(butylene succinate) in its mixtures with bisphenol A.CHINESE JOURNAL OF POLYMER SCIENCE,31(12),1685-1696.
MLA	Luo, Fa-liang,et al."Hydrogen-bonding induced change of crystallization behavior of poly(butylene succinate) in its mixtures with bisphenol A".CHINESE JOURNAL OF POLYMER SCIENCE 31.12(2013):1685-1696.