Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence | |
Shi, Yonghong1,2; Duan, Pengfei2; Huo, Shengwei2; Li, Yuangang1; Liu, Minghua2,3,4 | |
刊名 | ADVANCED MATERIALS |
2018-03-22 | |
卷号 | 30期号:12 |
关键词 | Chirality Transfer Circularly Polarized Luminescence Organogels Perovskite Nanocrystals Self-assembly |
ISSN号 | 0935-9648 |
DOI | 10.1002/adma.201705011 |
英文摘要 | Perovskite nanocrystals are attracting great interest due to their excellent photonic properties. Here, through a supramolecular self-assembly approach, the perovskite nanocrystals (NCs) with a novel circularly polarized luminescence (CPL) are successfully endowed. It is found that the achiral perovskite NCs can coassemble with chiral gelator in nonpolar solvents, in which the gelator molecules modify the surface of the perovskite NCs. Through such cogelation, the molecular chirality can transfer to the NCs resulting in CPL signals with a dissymmetric factor (g(lum)) up to 10(-3). Furthermore, depending on the molecular chirality of the gelator, the CPL sense can be selected and the mirror-imaged CPL is obtained. Such gels can be further embedded into the polymer film to facilitate flexible CPL devices. It is envisaged that this approach will afford a new insight into the designing of the functional chiroptical materials. |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000428348000006 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/45953] |
专题 | 中国科学院化学研究所 |
通讯作者 | Duan, Pengfei; Li, Yuangang; Liu, Minghua |
作者单位 | 1.Xian Univ Sci & Technol, Coll Chem & Chem Engn, 58 Yanta Rd, Xian 710054, Shaanxi, Peoples R China 2.Natl Ctr Nanosci & Technol NCNST, Div Nanophoton, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, 11 ZhongGuanCun BeiYiTiao, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid Interface & Chem Thermodynam, Inst Chem, 2 ZhongGuanCun BeiYiJie, Beijing 100190, Peoples R China 4.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China |
推荐引用方式 GB/T 7714 | Shi, Yonghong,Duan, Pengfei,Huo, Shengwei,et al. Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence[J]. ADVANCED MATERIALS,2018,30(12). |
APA | Shi, Yonghong,Duan, Pengfei,Huo, Shengwei,Li, Yuangang,&Liu, Minghua.(2018).Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence.ADVANCED MATERIALS,30(12). |
MLA | Shi, Yonghong,et al."Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence".ADVANCED MATERIALS 30.12(2018). |
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