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Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence
Shi, Yonghong1,2; Duan, Pengfei2; Huo, Shengwei2; Li, Yuangang1; Liu, Minghua2,3,4
刊名ADVANCED MATERIALS
2018-03-22
卷号30期号:12
关键词Chirality Transfer Circularly Polarized Luminescence Organogels Perovskite Nanocrystals Self-assembly
ISSN号0935-9648
DOI10.1002/adma.201705011
英文摘要Perovskite nanocrystals are attracting great interest due to their excellent photonic properties. Here, through a supramolecular self-assembly approach, the perovskite nanocrystals (NCs) with a novel circularly polarized luminescence (CPL) are successfully endowed. It is found that the achiral perovskite NCs can coassemble with chiral gelator in nonpolar solvents, in which the gelator molecules modify the surface of the perovskite NCs. Through such cogelation, the molecular chirality can transfer to the NCs resulting in CPL signals with a dissymmetric factor (g(lum)) up to 10(-3). Furthermore, depending on the molecular chirality of the gelator, the CPL sense can be selected and the mirror-imaged CPL is obtained. Such gels can be further embedded into the polymer film to facilitate flexible CPL devices. It is envisaged that this approach will afford a new insight into the designing of the functional chiroptical materials.
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000428348000006
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/45953]  
专题中国科学院化学研究所
通讯作者Duan, Pengfei; Li, Yuangang; Liu, Minghua
作者单位1.Xian Univ Sci & Technol, Coll Chem & Chem Engn, 58 Yanta Rd, Xian 710054, Shaanxi, Peoples R China
2.Natl Ctr Nanosci & Technol NCNST, Div Nanophoton, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, 11 ZhongGuanCun BeiYiTiao, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid Interface & Chem Thermodynam, Inst Chem, 2 ZhongGuanCun BeiYiJie, Beijing 100190, Peoples R China
4.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
推荐引用方式
GB/T 7714
Shi, Yonghong,Duan, Pengfei,Huo, Shengwei,et al. Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence[J]. ADVANCED MATERIALS,2018,30(12).
APA Shi, Yonghong,Duan, Pengfei,Huo, Shengwei,Li, Yuangang,&Liu, Minghua.(2018).Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence.ADVANCED MATERIALS,30(12).
MLA Shi, Yonghong,et al."Endowing Perovskite Nanocrystals with Circularly Polarized Luminescence".ADVANCED MATERIALS 30.12(2018).
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