Weakly Basic Anion Recognition by Naphthalenediimide-Based Polymer

doi:10.1002/ajoc.201700333

CORC > 化学研究所 > 中国科学院化学研究所

	Weakly Basic Anion Recognition by Naphthalenediimide-Based Polymer
	Yan, Jijun 1,2; Kang, Chuanqing 1; Ma, Xiaoye 1; Du, Zhijun 1; Bian, Zheng 1; Jin, Rizhe 1; Gao, Lianxun 1
刊名	ASIAN JOURNAL OF ORGANIC CHEMISTRY
	2017-11-01
卷号	6 期号:11 页码:1531-1535
关键词	Anion-pi Interactions Molecular Recognition Naphthalenediimides Self-assembly Weakly Basic Anion
ISSN号	2193-5807
DOI	10.1002/ajoc.201700333
英文摘要	The development of naphthalenediimide (NDI)based sensors for weakly basic anion recognition is an attractive challenge. This paper presents an NDI-based polymer for the recognition of weakly basic oxyanions (AcO-, PhCO2 (-), ClO4-, and IO4-) and halides (Cl-, Br-, and I-) through the formation of NDIC-bands and changes in the pi-pi* transition bands of the polymer in UV/Vis and circular dichroism spectra. The recognition results from anion-to-NDI thermal electron transfer and disturbance of the self-assembly of the polymer by anions. In particular, the formation of NDIC-induced by Cl-was observed, which is a distinctive advantage of the polymer in comparison with small molecular NDIs. The results demonstrate a practical approach to versatile functional materials through a combination of anion-NDI interactions and polymeric self-assembly.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000418149900003
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/45269]
专题	中国科学院化学研究所
通讯作者	Kang, Chuanqing
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yan, Jijun,Kang, Chuanqing,Ma, Xiaoye,et al. Weakly Basic Anion Recognition by Naphthalenediimide-Based Polymer[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2017,6(11):1531-1535.
APA	Yan, Jijun.,Kang, Chuanqing.,Ma, Xiaoye.,Du, Zhijun.,Bian, Zheng.,...&Gao, Lianxun.(2017).Weakly Basic Anion Recognition by Naphthalenediimide-Based Polymer.ASIAN JOURNAL OF ORGANIC CHEMISTRY,6(11),1531-1535.
MLA	Yan, Jijun,et al."Weakly Basic Anion Recognition by Naphthalenediimide-Based Polymer".ASIAN JOURNAL OF ORGANIC CHEMISTRY 6.11(2017):1531-1535.