Polythiophene-Peptide Biohybrid Assemblies for Enhancing Photoinduced Hydrogen Evolution

doi:10.1002/aelm.201700164

CORC > 化学研究所 > 中国科学院化学研究所

	Polythiophene-Peptide Biohybrid Assemblies for Enhancing Photoinduced Hydrogen Evolution
	Lu, Huan 1; Zhou, Chengcheng 1; Zhou, Xin 1; Sun, Han 1; Bai, Haotian 1; Wang, Yunxia 1; Lv, Fengting 1; Liu, Libing 1; Ma, Yuguo 2,3; Wang, Shu 1
刊名	ADVANCED ELECTRONIC MATERIALS
	2017-11-01
卷号	3 期号:11
关键词	Assemblies Hydrogen Evolution Peptides Photocatalysis Polythiophene
ISSN号	2199-160X
DOI	10.1002/aelm.201700164
英文摘要	The self-assembly of short peptide offers versatile processes for adjusting the ordered stacking of organic functional materials to enhance photoinduced electron transfer. Herein, this study presents the first demonstration of the use of A(16-22) peptide to prepare polythiophene/A(16-22) assemblies for a photocatalytic water splitting system. Isothermal titration microcalorimetry results show that the driving forces for polythiophene/A(16-22) assembly formation are electrostatic interactions, as well as hydrogen bonds and hydrophobic interactions. The assemblies accelerate the photoinduced electrons transfer from polythiophene upon light excitation and eventually enhance the hydrogen evolution. This work opens a new way into the development of biohybrid materials as novel photocatalytic water splitting platform for hydrogen evolution.
语种	英语
出版者	WILEY
WOS记录号	WOS:000416047700011
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/45079]
专题	中国科学院化学研究所
通讯作者	Lv, Fengting; Ma, Yuguo; Wang, Shu
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Ctr Soft Matter Sci & Engn, Coll Chem,Minist Educ, Beijing 100871, Peoples R China 3.Peking Univ, Minist Educ, Key Lab Polymer Chem & Phys, Coll Chem, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Lu, Huan,Zhou, Chengcheng,Zhou, Xin,et al. Polythiophene-Peptide Biohybrid Assemblies for Enhancing Photoinduced Hydrogen Evolution[J]. ADVANCED ELECTRONIC MATERIALS,2017,3(11).
APA	Lu, Huan.,Zhou, Chengcheng.,Zhou, Xin.,Sun, Han.,Bai, Haotian.,...&Wang, Shu.(2017).Polythiophene-Peptide Biohybrid Assemblies for Enhancing Photoinduced Hydrogen Evolution.ADVANCED ELECTRONIC MATERIALS,3(11).
MLA	Lu, Huan,et al."Polythiophene-Peptide Biohybrid Assemblies for Enhancing Photoinduced Hydrogen Evolution".ADVANCED ELECTRONIC MATERIALS 3.11(2017).