Core-Shell SiO2-PS Colloids with Controlled Eccentric Ratio | |
Li, Yitong1,2; Liu, Bing1 | |
刊名 | ACS MACRO LETTERS
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2017-11-01 | |
卷号 | 6期号:11页码:1315-1319 |
ISSN号 | 2161-1653 |
DOI | 10.1021/acsmacrolett.7b00629 |
英文摘要 | Precisely controlling microstructure of colloidal particles is crucial for their applications. Core-shell colloids have been extensively synthesized and used in past decades. However, controlling the location of cores in core-shell particles remains a challenge. To address this problem we explored the synthesis of SiO2-PS core-shell colloids by using a simple system containing only core particles, monomer, initiator, and water/ethanol and found the increase of ethanol/water ratio can induce a structure transition sequence from eccentric to concentric to eccentric to concentric to eccentric. Furthermore, we illustrate that the eccentric ratios of SiO2-PS core-shell colloids, that is, the location of SiO2 cores in the whole particles, can be precisely controlled by a two-step polymerization procedure. It is anticipated that our results can widen the application of core-shell colloids, especially after the introduction of functionality for core or shell materials. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000416500000026 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/45011] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Bing |
作者单位 | 1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, CAS Res Educ Ctr Excellence Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100149, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Yitong,Liu, Bing. Core-Shell SiO2-PS Colloids with Controlled Eccentric Ratio[J]. ACS MACRO LETTERS,2017,6(11):1315-1319. |
APA | Li, Yitong,&Liu, Bing.(2017).Core-Shell SiO2-PS Colloids with Controlled Eccentric Ratio.ACS MACRO LETTERS,6(11),1315-1319. |
MLA | Li, Yitong,et al."Core-Shell SiO2-PS Colloids with Controlled Eccentric Ratio".ACS MACRO LETTERS 6.11(2017):1315-1319. |
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