Palladium catalyzed C(sp(3))-H acetoxylation of aliphatic primary amines to gamma-amino alcohol derivatives

doi:10.1039/c7qo00432j

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	Palladium catalyzed C(sp(3))-H acetoxylation of aliphatic primary amines to gamma-amino alcohol derivatives
	Chen, Kang 1,2; Wang, Ding 1,2; Li, Zhao-Wei 1,2; Liu, Zheng 1,2; Pan, Fei 1,2; Zhang, Yun-Fei 1,2; Shi, Zhang-Jie 1,2,3
刊名	ORGANIC CHEMISTRY FRONTIERS
	2017-11-01
卷号	4 期号:11 页码:2097-2101
ISSN号	2052-4129
DOI	10.1039/c7qo00432j
英文摘要	It still remains a major challenge to apply free primary amino groups as the directing group for aliphatic C-H functionalization. In this article, we used the protonation strategy to control the binding ability of primary amines and realized free amino group directed inert aliphatic C-H acetoxylation in good chemo- and regio-selectivity. This methodology provided a straightforward approach from primary amines to gamma-amino alcohols.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000413826400002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/44995]
专题	中国科学院化学研究所
通讯作者	Shi, Zhang-Jie
作者单位	1.Peking Univ, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mlecular Engn, Minist Educ, Beijing 100871, Peoples R China 3.Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Chen, Kang,Wang, Ding,Li, Zhao-Wei,et al. Palladium catalyzed C(sp(3))-H acetoxylation of aliphatic primary amines to gamma-amino alcohol derivatives[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(11):2097-2101.
APA	Chen, Kang.,Wang, Ding.,Li, Zhao-Wei.,Liu, Zheng.,Pan, Fei.,...&Shi, Zhang-Jie.(2017).Palladium catalyzed C(sp(3))-H acetoxylation of aliphatic primary amines to gamma-amino alcohol derivatives.ORGANIC CHEMISTRY FRONTIERS,4(11),2097-2101.
MLA	Chen, Kang,et al."Palladium catalyzed C(sp(3))-H acetoxylation of aliphatic primary amines to gamma-amino alcohol derivatives".ORGANIC CHEMISTRY FRONTIERS 4.11(2017):2097-2101.