Crystal structure, spectral and electrochemical properties of [TBA](2)[Ni(i-MNT)(2)], [TBA][Ni(i-MNT)(2)], [TBA](2)[Ni(i-MNS)(2)] and related bis(1,2-dithiolene) metal complexes

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	Crystal structure, spectral and electrochemical properties of [TBA](2)[Ni(i-MNT)(2)], [TBA][Ni(i-MNT)(2)], [TBA](2)[Ni(i-MNS)(2)] and related bis(1,2-dithiolene) metal complexes
	Liu, SG; Liu, YQ; Li, YF; Zhu, DB
刊名	SYNTHETIC METALS
	1996-11-01
卷号	83 期号:2 页码:131-140
关键词	Bisdithiolene Metal Complex Crystal Structure Cyclic Voltammetry Spectra Conductivity
ISSN号	0379-6779
英文摘要	The synthesis, crystal structure and physical properties of bis(1,1-dithiolene) or bis(1,1-diselenolene) metal complexes of [TBA](2)[Ni(i-MNT)(2)], [TBA][Ni(i-MNT)(2)] and [TBA](2)[Ni(i-MNS)(2)] (i-MNT=2,2-dicyanoethylene-1,l-dithiolate, i-MNS=2,2-dicyanoethylene-1,1-diselenolate) were studied and compared to one another or to tie related bis(1,2-dithiolene) metal complexes of 5,6-dihydro-1,4-dithiin-2,3-dithiolate, 1,3-dithiole-2-thione-4,5-dithiolate and 1,3-dithiole-2-one-4,5-dithiolate ligands. The structures of the complexes contain equidistant anionic stacks well separated by the counter cation sheets. The planarity and short C-S or C-Se distances in the structures indicate extensive delocalization of the pi-system in the compounds. The relative low conductivities for the complexes are due to the low polarizability,large intra- and inter-stack S ... S distances, and the relative high on-site electron-electron repulsion energy in the compounds.
语种	英语
出版者	ELSEVIER SCIENCE SA LAUSANNE
WOS记录号	WOS:A1996WT90400011
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/44649]
专题	中国科学院化学研究所
作者单位	CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA
推荐引用方式 GB/T 7714	Liu, SG,Liu, YQ,Li, YF,et al. Crystal structure, spectral and electrochemical properties of [TBA](2)[Ni(i-MNT)(2)], [TBA][Ni(i-MNT)(2)], [TBA](2)[Ni(i-MNS)(2)] and related bis(1,2-dithiolene) metal complexes[J]. SYNTHETIC METALS,1996,83(2):131-140.
APA	Liu, SG,Liu, YQ,Li, YF,&Zhu, DB.(1996).Crystal structure, spectral and electrochemical properties of [TBA](2)[Ni(i-MNT)(2)], [TBA][Ni(i-MNT)(2)], [TBA](2)[Ni(i-MNS)(2)] and related bis(1,2-dithiolene) metal complexes.SYNTHETIC METALS,83(2),131-140.
MLA	Liu, SG,et al."Crystal structure, spectral and electrochemical properties of [TBA](2)[Ni(i-MNT)(2)], [TBA][Ni(i-MNT)(2)], [TBA](2)[Ni(i-MNS)(2)] and related bis(1,2-dithiolene) metal complexes".SYNTHETIC METALS 83.2(1996):131-140.