Yielding Behavior in Colloidal Glasses: Comparison between "Hard Cage" and "Soft Cage"

doi:10.1021/la500866d

CORC > 化学研究所 > 中国科学院化学研究所

	Yielding Behavior in Colloidal Glasses: Comparison between "Hard Cage" and "Soft Cage"
	Zhou, Zhi 1,2; Hollingsworth, Javoris V.1; Hong, Song 3; Cheng, He 4; Han, Charles C.1
刊名	LANGMUIR
	2014-05-27
卷号	30 期号:20 页码:5739-5746
ISSN号	0743-7463
DOI	10.1021/la500866d
英文摘要	Rheological measurements are utilized to examine the yielding behavior of a polystyrene (PS) core and poly(N-isopropylacrylamide) (PNIPAM) shell microgel system with varying shell/core ratio. For a shell/core ratio of 0.15 at high concentrations, the suspensions show a typical hard sphere (HS) yielding response where the loss modulus (G '') exhibits a single peak due to cage breaking. As a result of tighter cages and less cage distortion prior to yielding, the peak location of G '' decreases with volume fraction. For a shell/core ratio of 1.10, which behaves like a soft jammed glass at high concentration, the suspensions exhibit a one-step yielding behavior similar to that of HS glass. However, the location of the peak in G '' increases with volume fraction, demonstrating the important role of particle deformation in the breakage of cages. For an intermediate shell/core ratio of 0.34, the system displays a two-step yielding behavior, as observed in previous reports for attractive glasses. By increasing the volume fraction, the strain of the first peak increases while the second one decreases. In addition, as the effective volume fraction increases to 112%, the two peaks merge into one broad peak. It is demonstrated that the first peak of G '' is due to deformation of the shell, and the second peak of G '' is attributed to cage breaking as a result of the cores colliding with each other. Combining these results, a yielding state diagram from typical HS to soft jammed glass is demonstrated.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000336641700008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/43545]
专题	中国科学院化学研究所
通讯作者	Cheng, He
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Beijing Univ Chem Technol, Anal & Test Ctr, Beijing 10029, Peoples R China 4.Inst High Energy Phys, China Spallat Neutron Source, Dongguan 523803, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Zhi,Hollingsworth, Javoris V.,Hong, Song,et al. Yielding Behavior in Colloidal Glasses: Comparison between "Hard Cage" and "Soft Cage"[J]. LANGMUIR,2014,30(20):5739-5746.
APA	Zhou, Zhi,Hollingsworth, Javoris V.,Hong, Song,Cheng, He,&Han, Charles C..(2014).Yielding Behavior in Colloidal Glasses: Comparison between "Hard Cage" and "Soft Cage".LANGMUIR,30(20),5739-5746.
MLA	Zhou, Zhi,et al."Yielding Behavior in Colloidal Glasses: Comparison between "Hard Cage" and "Soft Cage"".LANGMUIR 30.20(2014):5739-5746.