Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers

doi:10.1002/anie.201801289

CORC > 化学研究所 > 中国科学院化学研究所

	Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers
	Yuan, Kuo 1,2; Song, Tianqun 1,2; Wang, Dawei 3; Zhang, Xiaotao 1,2; Gao, Xiong 1,2; Zou, Ye 4; Dong, Huanli 4; Tang, Zhiyong 3; Hu, Wenping 1,2,4
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2018-05-14
卷号	57 期号:20 页码:5708-5713
关键词	Hydrogenation Hydrophobicity Metal-organic Frameworks Nanoparticles Polymers
ISSN号	1433-7851
DOI	10.1002/anie.201801289
英文摘要	Metal-organic frameworks (MOFs) as selectivity regulators for catalytic reactions have attracted much attention, especially MOFs and metal nanoparticle (NP) shelled structures, e.g., MOFs@NPs@MOFs. Nevertheless, making hydrophilic MOF shells for gathering hydrophobic reactants is challenging. Described here is a new and viable approach employing conjugated micro- and mesoporous polymers with iron(III) porphyrin (FeP-CMPs) as a new shell to fabricate MIL-101@Pt@FeP-CMP. It is not only hydrophobic and porous for enriching reactants, but also possesses iron sites to activate C=O bonds, thereby regulating the selectivity for cinnamyl alcohol in the hydrogenation of cinnamaldehyde. Interestingly, MIL-101@Pt@FeP-CMPsponge can achieve a high turnover frequency (1516.1 h(-1)), with 97.3% selectivity for cinnamyl alcohol at 97.6% conversion.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000431488200021
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/43115]
专题	中国科学院化学研究所
通讯作者	Zhang, Xiaotao; Tang, Zhiyong; Hu, Wenping
作者单位	1.Tianjin Univ, Tianjin Key Lab Mol Optoelect Sci, Dept Chem, Sch Sci, Tianjin 300072, Peoples R China 2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China 3.Chinese Acad Sci, Key Lab Nanosyst & Hierarchy Fabricat, CAS Ctr Excellence Nanosci, Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yuan, Kuo,Song, Tianqun,Wang, Dawei,et al. Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(20):5708-5713.
APA	Yuan, Kuo.,Song, Tianqun.,Wang, Dawei.,Zhang, Xiaotao.,Gao, Xiong.,...&Hu, Wenping.(2018).Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(20),5708-5713.
MLA	Yuan, Kuo,et al."Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.20(2018):5708-5713.