Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines

doi:10.1039/c7qi00803a

CORC > 化学研究所 > 中国科学院化学研究所

	Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines
	Zhu, Yanan 1,2; Yang, Shuliang 1; Cao, Changyan 1,2; Song, Weiguo 1,2; Wan, Li-Jun 1
刊名	INORGANIC CHEMISTRY FRONTIERS
	2018-05-01
卷号	5 期号:5 页码:1094-1099
ISSN号	2052-1553
DOI	10.1039/c7qi00803a
英文摘要	Selective hydrogenation of nitroarenes is an important chemical transformation to obtain functionalized anilines as key intermediates for pharmaceuticals and fine chemicals. Compared to the well-studied noble metal catalysts, heterogeneous catalysts based on low-cost transition metals are rarely reported. In this study, we developed an efficient and controllable route to synthesize a new kind of heterogeneous catalyst of iron phosphide nanoparticles encapsulated in a doped carbon matrix for the chemoselective hydrogenation of aromatic nitroarenes to anilines. Making use of the chemical reaction between Fe atoms in a MIL-88B-NH2 core and phosphorus atoms in a poly(cyclotriphosphazene-co-4,4-sulfonyldiphenol) (PZS) shell, iron phosphide nanoparticles encapsulated in a doped carbon matrix were successfully prepared through direct calcinations of a Fe-MOF@PZS core@shell precursor at 900 degrees C for 2 h under an Ar atmosphere. Due to the relative high surface area and porous structure as well as small nanoparticles, the prepared catalyst showed high catalytic activity, excellent selectivity and recyclability for the hydrogenation of aromatic nitroarenes to anilines.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000432586100012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/42949]
专题	中国科学院化学研究所
通讯作者	Cao, Changyan; Song, Weiguo
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Lab Mol Nanostruct & Nanotechnol, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Yanan,Yang, Shuliang,Cao, Changyan,et al. Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines[J]. INORGANIC CHEMISTRY FRONTIERS,2018,5(5):1094-1099.
APA	Zhu, Yanan,Yang, Shuliang,Cao, Changyan,Song, Weiguo,&Wan, Li-Jun.(2018).Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines.INORGANIC CHEMISTRY FRONTIERS,5(5),1094-1099.
MLA	Zhu, Yanan,et al."Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines".INORGANIC CHEMISTRY FRONTIERS 5.5(2018):1094-1099.