Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols

doi:10.1002/cctc.201900010

	Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols
	Jiang, Biao-Lin 1,4; Ma, Shuang-Shuang 2,3; Wang, Meng-Liang 1; Liu, Dian-Sheng 1; Xu, Bao-Hua 2,3; Zhang, Suo-Jiang 2,3
刊名	CHEMCATCHEM
	2019-03-20
卷号	11 期号:6 页码:1701-1706
关键词	bidentate ligand chemoselective reduction cobalt complex homogeneous catalysis transfer hydrogenation
ISSN号	1867-3880
DOI	10.1002/cctc.201900010
英文摘要	An environmentally benign protocol of chemoselective transfer hydrogenation of C=C and C=O bonds with alkanols under base-free conditions is developed by this study, wherein the cobalt-bidentate phosphine catalyst precursor is commercially available and the active low-valent Co species could be generated in-situ. For the conjugation enones, the vinyl group is selectively reduced, whereas with nonconjugated alkenones, the selectivity is changed to the carbonyl group. Besides, orthoalkenyl-benzaldehydes/imines are well tolerated, and the reduction solely occurs at the C=O/C=N site with this protocol.
资助项目	National Basic Research Program of China (973 Program)[2015CB251401] ; National Natural Science Foundation of China (Petrochemical Joint Fund)[U1662133]
WOS关键词	ASYMMETRIC TRANSFER HYDROGENATION ; ENANTIOSELECTIVE TRANSFER HYDROGENATION ; BIOMIMETIC TRANSFER HYDROGENATION ; ALPHA-ALKYLATION ; N-ALKYLATION ; SELECTIVE ALKYLATION ; CARBONYL-COMPOUNDS ; AROMATIC-AMINES ; IRON COMPLEXES ; KETONES
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000463960000018
资助机构	National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China (Petrochemical Joint Fund)
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/28280]
专题	中国科学院过程工程研究所
通讯作者	Xu, Bao-Hua
作者单位	1.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 4.Inst Proc Engn, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Biao-Lin,Ma, Shuang-Shuang,Wang, Meng-Liang,et al. Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols[J]. CHEMCATCHEM,2019,11(6):1701-1706.
APA	Jiang, Biao-Lin,Ma, Shuang-Shuang,Wang, Meng-Liang,Liu, Dian-Sheng,Xu, Bao-Hua,&Zhang, Suo-Jiang.(2019).Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols.CHEMCATCHEM,11(6),1701-1706.
MLA	Jiang, Biao-Lin,et al."Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols".CHEMCATCHEM 11.6(2019):1701-1706.