Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction

doi:10.1039/c8nj05643a

	Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction
	Qi, Xiaoxia 1; Yan, Xirui 1; Peng, Wencai 1,2; Zhang, Jianshu 1,2; Tong, Yanbin 1; Li, Jun 3; Sun, Dekui 4; Hui, Ge 4; Zhang, Jinli 1,5
刊名	NEW JOURNAL OF CHEMISTRY
	2019-03-28
卷号	43 期号:12 页码:4698-4705
ISSN号	1144-0546
DOI	10.1039/c8nj05643a
英文摘要	Hierarchical mesoporous MgO (HMM) is synthesized in the presence of graphene by a simple hydrothermal homogeneous precipitation route using urea as the precipitating reagent. Characterization of the HMM particles by means of spectroscopy and microscopy techniques, among others, indicates that HMM exposes the (111) crystal faces and possesses a specific surface area of 138 m(2) g(-1) and a pore size of about 0.33 m(2) g(-1). HMM exhibits higher activity for the Claisen-Schmidt condensation reaction than a conventionally prepared MgO catalyst, with a maximum turn over frequency of 1.34 x 10(-4) s(-1). Since the deactivation of the catalyst is mainly due to the formation of polyaromatic ketones in the reaction process, the catalyst can be readily regenerated through calcination.
资助项目	Applied basic Research Program of Xinjiang Production and Construction Corps[2015AG400] ; Science & Technology Research and Achievement Transformation Project of Xinjiang Production and Construction Corps[2015AD027] ; Research Project of High-Level Talents Research of Shihezi University[RCZX201409] ; Training Program for Young Key Teachers of Shihezi University[CZ0211]
WOS关键词	CATALYTIC PERFORMANCE ; CHALCONES ; REDUCTION ; OXIDE ; ANALOGS ; NO
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000462541900004
资助机构	Applied basic Research Program of Xinjiang Production and Construction Corps ; Science & Technology Research and Achievement Transformation Project of Xinjiang Production and Construction Corps ; Research Project of High-Level Talents Research of Shihezi University ; Training Program for Young Key Teachers of Shihezi University
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/28272]
专题	中国科学院过程工程研究所
通讯作者	Peng, Wencai; Li, Jun
作者单位	1.Shihezi Univ, Sch Chem & Chem Engn, Shihezi 832003, Xinjiang, Peoples R China 2.Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi, Xinjiang, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan, Shanxi, Peoples R China 5.Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Chem Engn Tianj, Key Lab Syst Bioengn MOE, Tianjin 300072, Peoples R China
推荐引用方式 GB/T 7714	Qi, Xiaoxia,Yan, Xirui,Peng, Wencai,et al. Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction[J]. NEW JOURNAL OF CHEMISTRY,2019,43(12):4698-4705.
APA	Qi, Xiaoxia.,Yan, Xirui.,Peng, Wencai.,Zhang, Jianshu.,Tong, Yanbin.,...&Zhang, Jinli.(2019).Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction.NEW JOURNAL OF CHEMISTRY,43(12),4698-4705.
MLA	Qi, Xiaoxia,et al."Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction".NEW JOURNAL OF CHEMISTRY 43.12(2019):4698-4705.