Exploring the Interactions of Oxygen with Defective ZnO | |
Wang, X (Wang, Xuan)[ 1,2 ]; Lu, B (Lu, Bin)[ 1,3 ]; Li, L (Li, Ling)[ 1,2 ]; Qiu, HS (Qiu, Hengshan)[ 1 ] | |
刊名 | CHEMISTRYOPEN |
2018 | |
卷号 | 7期号:7页码:491-494 |
关键词 | activation energy adsorption bulk diffusion defective ZnO sensors |
ISSN号 | 2191-1363 |
DOI | 10.1002/open.201800044 |
英文摘要 | Exploring the interactions of oxygen with defective oxide is of importance to understand the microscopic process and performance of ZnO-based oxygen sensors. The interactions of environmental oxygen with vacuum-annealed defective ZnO have been studied by electrical methods, vacuum Fourier transform infrared spectroscopy, and in situ adsorption experiments. It was found that the vacuum-annealed defective ZnO exhibits varied electrical response at different temperatures, which, by vacuum IR investigation, was ascribed to the subtle balance between formation of oxygen vacancies and their interactions with environmental oxygen. Further studies showed that two microscopic steps including surface adsorption and bulk diffusion were dominating the interactions between defective ZnO and environmental oxygen, and the corresponding apparent activation energies were estimated to be 0.093 and 0.67eV through in situ adsorption experiments. The quite low activation barrier of oxygen adsorption on the defective ZnO was proposed to be responsible for the extreme high sensitivity of ZnO-based oxygen sensors. |
WOS记录号 | WOS:000440286200001 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/5787] |
专题 | 新疆理化技术研究所_环境科学与技术研究室 |
作者单位 | 1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Lab Environm Sci & Technol, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Wuhan Univ Technol, Sch Mat Sci & Engn, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, X ,Lu, B ,Li, L ,et al. Exploring the Interactions of Oxygen with Defective ZnO[J]. CHEMISTRYOPEN,2018,7(7):491-494. |
APA | Wang, X ,Lu, B ,Li, L ,&Qiu, HS .(2018).Exploring the Interactions of Oxygen with Defective ZnO.CHEMISTRYOPEN,7(7),491-494. |
MLA | Wang, X ,et al."Exploring the Interactions of Oxygen with Defective ZnO".CHEMISTRYOPEN 7.7(2018):491-494. |
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