Mild pyrolysis of ionic self-assembled cobalt porphyrins on carbon toward efficient electrochemical conversion of CO2 to CO

doi:10.1039/c9cc02156f

	Mild pyrolysis of ionic self-assembled cobalt porphyrins on carbon toward efficient electrochemical conversion of CO2 to CO
	Zhang, Xue 3; Liu, Huiyuan 1,2,3; Qin, Jiaqi 3; Han, Hongsa 3; Qiu, Chenxi 3; Zhang, Siyu 3; Hao, Xinyu 3; Liu, Wei 3; Song, Yujiang 3
刊名	CHEMICAL COMMUNICATIONS
	2019-05-14
卷号	55 期号:39 页码:5659-5662
ISSN号	1359-7345
DOI	10.1039/c9cc02156f
通讯作者	Song, Yujiang(yjsong@dlut.edu.cn)
英文摘要	We report ionic self-assembly of two oppositely charged cobalt(QIII) porphyrins (CoPs) on carbon coupled with subsequent mild pyrolysis at 350 degrees C, making CoPs lose some peripheral groups and become tightly adsorbed on the carbon with a high faradaic efficiency of 88 +/- 1.5% and a current density of 8 mA cm(-2) at a low overpotential of 430 mV toward electrochemical conversion of CO2 to CO.
资助项目	National Key Research & Development Program of China[2016YFB0101307] ; National Natural Science Foundation of China[21003114] ; National Natural Science Foundation of China[21103163] ; National Natural Science Foundation of China[21306188] ; National Natural Science Foundation of China[21373211] ; National Natural Science Foundation of China[21306187] ; Liaoning BaiQianWan Talents Program[201519] ; Program for Liaoning Excellent Talents in University[LR201514] ; Dalian Excellent Young Scientific and Technological Talents[2015R006] ; Fundamental Research Funds for the Central Universities[DUT15RC(3)001] ; Fundamental Research Funds for the Central Universities[DUT15ZD225]
WOS关键词	COVALENT ORGANIC FRAMEWORKS ; N-C ; REDUCTION ; CATALYST ; DIOXIDE ; ELECTROREDUCTION ; PERFORMANCE ; NANOCRYSTALS ; NANOTUBES ; SITES
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000468401700026
资助机构	National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Program for Liaoning Excellent Talents in University ; Program for Liaoning Excellent Talents in University ; Dalian Excellent Young Scientific and Technological Talents ; Dalian Excellent Young Scientific and Technological Talents ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Program for Liaoning Excellent Talents in University ; Program for Liaoning Excellent Talents in University ; Dalian Excellent Young Scientific and Technological Talents ; Dalian Excellent Young Scientific and Technological Talents ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Program for Liaoning Excellent Talents in University ; Program for Liaoning Excellent Talents in University ; Dalian Excellent Young Scientific and Technological Talents ; Dalian Excellent Young Scientific and Technological Talents ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Program for Liaoning Excellent Talents in University ; Program for Liaoning Excellent Talents in University ; Dalian Excellent Young Scientific and Technological Talents ; Dalian Excellent Young Scientific and Technological Talents ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171845]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Song, Yujiang
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Labs Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xue,Liu, Huiyuan,Qin, Jiaqi,et al. Mild pyrolysis of ionic self-assembled cobalt porphyrins on carbon toward efficient electrochemical conversion of CO2 to CO[J]. CHEMICAL COMMUNICATIONS,2019,55(39):5659-5662.
APA	Zhang, Xue.,Liu, Huiyuan.,Qin, Jiaqi.,Han, Hongsa.,Qiu, Chenxi.,...&Song, Yujiang.(2019).Mild pyrolysis of ionic self-assembled cobalt porphyrins on carbon toward efficient electrochemical conversion of CO2 to CO.CHEMICAL COMMUNICATIONS,55(39),5659-5662.
MLA	Zhang, Xue,et al."Mild pyrolysis of ionic self-assembled cobalt porphyrins on carbon toward efficient electrochemical conversion of CO2 to CO".CHEMICAL COMMUNICATIONS 55.39(2019):5659-5662.