Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation

doi:10.1021/acs.organomet.5b00957

	Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation
	Xu, Ling 2; Wang, Yang 2; Wang, Yu-Chen 2; Wang, Zitao 2; Zhang, Wen-Xiong 1,2; Xi, Zhenfeng 2
刊名	ORGANOMETALLICS
	2016-01-11
卷号	35 期号:1 页码:5-8
ISSN号	0276-7333
DOI	10.1021/acs.organomet.5b00957
文献子类	Article
英文摘要	The sandwich lutetacyclopentadiene 2 can be obtained in high yield by the 1:1 reaction of the 1,4-dilithio-1,3-butadiene 1 with [Cp2LuCl]. Single-crystal X-ray diffraction of 2 reveals it as a contact ion pair with the coordination of lithium to the diene unit. This coordination mode is rare in metallacyclopentadiene chemistry. Further transformation of 2 with the inorganic salt KF and crown ethers leads to the formation of sandwich lutetacyclopentadienes 3 and 5 as separated ion pairs and of 4 as a one-dimensional coordination polymer.
WOS关键词	MOLECULAR-STRUCTURE ; CRYSTAL-STRUCTURE ; BUILDING-BLOCK ; METAL CENTER ; COMPLEXES ; REACTIVITY ; METALLACYCLOPENTADIENES ; LIGANDS ; METALLOCENES ; MOLYBDENUM
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000368048000002
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171500]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhang, Wen-Xiong
作者单位	1.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci,Minist Educ, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Xu, Ling,Wang, Yang,Wang, Yu-Chen,et al. Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation[J]. ORGANOMETALLICS,2016,35(1):5-8.
APA	Xu, Ling,Wang, Yang,Wang, Yu-Chen,Wang, Zitao,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2016).Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation.ORGANOMETALLICS,35(1),5-8.
MLA	Xu, Ling,et al."Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation".ORGANOMETALLICS 35.1(2016):5-8.