Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst

doi:10.1002/cssc.201501506

	Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst
	Xu, Shutao 1; Lei, Nian 2,3; Wang, Jia 2,3; Zhao, Xiaochen 2; Li, Lin 2; Zhang, Leilei 2; Miao, Shu 2; Pan, Xiaoli 2; Wang, Aiqin 2; Zhang, Tao 2
刊名	CHEMSUSCHEM
	2016-04-21
卷号	9 期号:8 页码:784-790
关键词	Glycerol Hydrogenolysis Supported Catalysts Tungsten Oxide 1 3-propanediol
ISSN号	1864-5631
DOI	10.1002/cssc.201501506
文献子类	Article
英文摘要	Single/pseudo-single atom Pt catalyst was prepared on mesoporous WOx. The large surface area and abundant oxygen vacancies of WOx improve the Pt dispersion and stabilize the Pt isolation. This newly prepared catalyst exhibited outstanding hydrogenolysis activity under 1 MPa H-2 pressure with a very high space-time yield towards 1,3-propanediol (3.78 g g(Pt)(-1) h(-1)) in Pt-W catalysts. The highly isolated Pt structure is thought to contribute to the excellent H-2 dissociation capacity over Pt/WOx. The high selectivity towards 1,3-propanediol is attributed to the heterolytic dissociation of H-2 at the interface of Pt and WOx (providing specific Bronsted acid sites and the concerted dehydration-hydrogenation reaction) and the bond formation between glycerol and WOx, which favors/stabilizes the formation of a secondary carbocation intermediate as well as triggers the redox cycle of the W species (W6+ reversible arrow QW(5+)).
WOS关键词	SELECTIVE HYDROGENOLYSIS ; IRIDIUM CATALYST ; CHEMICALS ; NANOSTRUCTURES ; OXIDATION ; BEHAVIOR ; POLYOLS ; METALS ; FILMS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000375113800002
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170856]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Aiqin; Zhang, Tao
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Xu, Shutao,Lei, Nian,Wang, Jia,et al. Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst[J]. CHEMSUSCHEM,2016,9(8):784-790.
APA	Xu, Shutao.,Lei, Nian.,Wang, Jia.,Zhao, Xiaochen.,Li, Lin.,...&Zhang, Tao.(2016).Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst.CHEMSUSCHEM,9(8),784-790.
MLA	Xu, Shutao,et al."Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst".CHEMSUSCHEM 9.8(2016):784-790.