Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal [3+2] cycloaddition of propargylic esters with beta-keto phosphonates

doi:10.1016/S1872-2067(16)62488-9

	Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal [3+2] cycloaddition of propargylic esters with beta-keto phosphonates
	Chen, Xiushuai 1,2; Li, Qing 1,2; Hu, Xiangping 2; Liu, Yanjun 1; Hou, Chuanjin 1; Yang, Ruifeng 1
刊名	CHINESE JOURNAL OF CATALYSIS
	2016-08-01
卷号	37 期号:8 页码:1389-1395
关键词	Copper Asymmetric Synthesis [3+2] Cycloaddition Beta-keto Phosphonates Phosphonylated 2 3-dihydrofurans
ISSN号	0253-9837
DOI	10.1016/S1872-2067(16)62488-9
文献子类	Article
英文摘要	Copper catalyzed asymmetric formal [3+2] cycloaddition of propargylic esters to beta-keto phosphonates for the synthesis of chiral phosphonylated 2,3-dihydrofurans was developed. By using a bulky and structurally rigid tridentate ketimine P,N,N ligand, a series of optically active phosphonylated 2,3-dihydrofurans were prepared in high yield and up to 92% ee. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS关键词	FEIST-BENARY REACTIONS ; ALKYLATION REACTION ; DIHYDROFURANS ; SUBSTITUTION ; AMINATION ; DERIVATIVES ; KETOESTERS ; ENAMINES ; TRIFLATE ; ACETATES
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000381326900025
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170118]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Hu, Xiangping; Liu, Yanjun; Hou, Chuanjin
作者单位	1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Chen, Xiushuai,Li, Qing,Hu, Xiangping,et al. Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal [3+2] cycloaddition of propargylic esters with beta-keto phosphonates[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(8):1389-1395.
APA	Chen, Xiushuai,Li, Qing,Hu, Xiangping,Liu, Yanjun,Hou, Chuanjin,&Yang, Ruifeng.(2016).Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal [3+2] cycloaddition of propargylic esters with beta-keto phosphonates.CHINESE JOURNAL OF CATALYSIS,37(8),1389-1395.
MLA	Chen, Xiushuai,et al."Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal [3+2] cycloaddition of propargylic esters with beta-keto phosphonates".CHINESE JOURNAL OF CATALYSIS 37.8(2016):1389-1395.