Two-Step, Catalytic C-C Bond Oxidative Cleavage Process Converts Lignin Models and Extracts to Aromatic Acids

doi:10.1021/acscatal.6b02049

	Two-Step, Catalytic C-C Bond Oxidative Cleavage Process Converts Lignin Models and Extracts to Aromatic Acids
	Lu, Jianmin 1; Wang, Min 1; Zhang, Xiaochen 1; Li, Lihua 1; Li, Hongji 1,2; Luo, Nengchao 1,2; Wang, Feng 1
刊名	ACS CATALYSIS
	2016-09-01
卷号	6 期号:9 页码:6086-6090
关键词	Lignin Biomass Oxidation Copper C-c Cleavage
ISSN号	2155-5435
DOI	10.1021/acscatal.6b02049
文献子类	Article
英文摘要	We herein report a two-step strategy for oxidative cleavage of lignin C-C bond to aromatic acids and phenols with molecular oxygen as oxidant. In the first step, lignin beta-O-4 alcohol was oxidized to beta-O-4 ketone over a VOSO4/TEMPO [(2,2,6,6-tetramethy1piperidin-1-yl)oxyl)] catalyst. In the second step, the C-C bond of beta-O-4 linkages was selectively cleaved to acids and phenols by oxidation over a Cu/1,10-phenanthroline catalyst. Computational investigations suggested a copper-oxo-bridged dimer was the catalytically active site for hydrogen-abstraction from C-beta-H bond, which was the rate-determining step for the C-C bond cleavage.
WOS关键词	COPPER-DIOXYGEN ADDUCT ; ARYL ETHERS ; O BONDS ; VANADIUM CATALYST ; AEROBIC OXIDATION ; MOLECULAR-OXYGEN ; FORMIC-ACID ; WOOD LIGNIN ; HYDROGENOLYSIS ; DEPOLYMERIZATION
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000382714000050
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170116]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Feng
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Lu, Jianmin,Wang, Min,Zhang, Xiaochen,et al. Two-Step, Catalytic C-C Bond Oxidative Cleavage Process Converts Lignin Models and Extracts to Aromatic Acids[J]. ACS CATALYSIS,2016,6(9):6086-6090.
APA	Lu, Jianmin.,Wang, Min.,Zhang, Xiaochen.,Li, Lihua.,Li, Hongji.,...&Wang, Feng.(2016).Two-Step, Catalytic C-C Bond Oxidative Cleavage Process Converts Lignin Models and Extracts to Aromatic Acids.ACS CATALYSIS,6(9),6086-6090.
MLA	Lu, Jianmin,et al."Two-Step, Catalytic C-C Bond Oxidative Cleavage Process Converts Lignin Models and Extracts to Aromatic Acids".ACS CATALYSIS 6.9(2016):6086-6090.