Facile Synthesis of Dodecamine Organic Cage-Based Monolithic Microreactor via Ring-Opening Polymerization Following Spontaneous Reduction of Gold Ions for Continuous Flow Catalysis

doi:10.1002/slct.201702213

	Facile Synthesis of Dodecamine Organic Cage-Based Monolithic Microreactor via Ring-Opening Polymerization Following Spontaneous Reduction of Gold Ions for Continuous Flow Catalysis
	Li, Ya 1; Peng, Xiaojun 2; Liu, Zhongshan 1; Ye, Mingliang 1; Wang, Hongwei 1,2; Ou, Junjie 1; Chen, Lianfang 1
刊名	CHEMISTRYSELECT
	2017-11-21
卷号	2 期号:33 页码:10880-10884
关键词	Continuous Flow Catalysis Dodecaamide Organic Cage Gold Nanoparticles Monolithic Microreactor Spontaneous Reduction
ISSN号	2365-6549
DOI	10.1002/slct.201702213
文献子类	Article
英文摘要	The reduction product of imine-based porous organic cage CC1, namely dodecamine organic cage RCC1, was introduced as a novel crosslinker in fabrication of polymeric monolith by ring-opening polymerization with ethylene glycol diglycidyl ether (EGDGE). Due to the presence of amines in polymeric matrix, poly(RCC1-co-EGDGE) monoliths could be employed as dual functional reductant and stabilizer in the formation of gold nanoparticles (AuNPs) on their surface by spontaneous reduction of Au3+ to Au-0. The immobilized AuNPs, together with micrometer-scale macropores of the monolith, provided the feasibility of continuous flow catalysis. Then AuNPs-immobilized poly(RCC1-co-EGDGE) monolith (150 mm i.d. x 28 cm in length) was used as a catalytic microreactor in reduction of 8-nitroquinoline to 8-aminoquinoline. The reactant in the outflow completely disappeared, and high-yield product could be conveniently collected, indicating the promising of RCC1-based monolithic microreactor in catalysis.
WOS关键词	LIQUID-CHROMATOGRAPHY ; NANOPARTICLES ; CHEMISTRY ; REACTORS ; PERFORMANCE ; SEPARATION ; COLUMNS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000417742200040
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169224]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Ye, Mingliang; Ou, Junjie
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian, Peoples R China 2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Li, Ya,Peng, Xiaojun,Liu, Zhongshan,et al. Facile Synthesis of Dodecamine Organic Cage-Based Monolithic Microreactor via Ring-Opening Polymerization Following Spontaneous Reduction of Gold Ions for Continuous Flow Catalysis[J]. CHEMISTRYSELECT,2017,2(33):10880-10884.
APA	Li, Ya.,Peng, Xiaojun.,Liu, Zhongshan.,Ye, Mingliang.,Wang, Hongwei.,...&Chen, Lianfang.(2017).Facile Synthesis of Dodecamine Organic Cage-Based Monolithic Microreactor via Ring-Opening Polymerization Following Spontaneous Reduction of Gold Ions for Continuous Flow Catalysis.CHEMISTRYSELECT,2(33),10880-10884.
MLA	Li, Ya,et al."Facile Synthesis of Dodecamine Organic Cage-Based Monolithic Microreactor via Ring-Opening Polymerization Following Spontaneous Reduction of Gold Ions for Continuous Flow Catalysis".CHEMISTRYSELECT 2.33(2017):10880-10884.