Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin

doi:10.1021/acssuschemeng.8b00757

	Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin
	Cong, Yu 1; Tang, Hao 1,2; Li, Ning 1,3; Li, Guangyi 1; Wang, Wentao 1; Wang, Aiqin 1,3; Wang, Xiaodong 1
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2018-04-01
卷号	6 期号:4 页码:5645-5652
关键词	Carbohydrates Dehydration 5-hydroxymethylfurfural Lignosulfonate Acidic Resin
ISSN号	2168-0485
DOI	10.1021/acssuschemeng.8b00757
文献子类	Article
英文摘要	Lignosulfonate-based renewable solid acids were first utilized as effective catalysts for fructose dehydration to produce 5-hydroxymethylfurfural (HMF). Among the investigated catalysts, the LF resin synthesized with formaldehyde and sodium lignosulfonate demonstrated the highest activity and good stability. Over it, similar to 90% HMF carbon yield was reached at 393 K. On the basis of the characterization results of N-2-physisorption, chemical titration, and microcalorimetric measurement of NH3 adsorption, the outstanding performance of LF resin should be interpreted by its higher acid strength and/or the synergistic effect of adjacent -SO3H, -COOH and phenolic -OH surface functional groups. We also explored the applicability of the LF resin for HMF production using other cheaper carbohydrates. Here, 73% HMF carbon yield was obtained from inulin hydrolysis/dehydration after the reaction was conducted over the LF resin at 393 K for 2.5 h.
WOS关键词	TEMPERATURE CARBON MATERIALS ; HIGH-YIELD PRODUCTION ; AEROBIC OXIDATION ; SOLID ACID ; 2,5-FURANDICARBOXYLIC ACID ; CATALYTIC CONVERSION ; EFFICIENT PRODUCTION ; BIOMASS ; CHEMICALS ; SO3H
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000429285800133
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168998]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Ning
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 4S7 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM Collaborat Innovat Ctr Chem Energy Mat, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Cong, Yu,Tang, Hao,Li, Ning,et al. Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(4):5645-5652.
APA	Cong, Yu.,Tang, Hao.,Li, Ning.,Li, Guangyi.,Wang, Wentao.,...&Wang, Xiaodong.(2018).Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(4),5645-5652.
MLA	Cong, Yu,et al."Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.4(2018):5645-5652.