Engineering Fractal MTW Zeolite Mesocrystal: Particle-Based Dendritic Growth via Twinning-Plane Induced Crystallization

doi:10.1021/acs.cgd.7b01547

	Engineering Fractal MTW Zeolite Mesocrystal: Particle-Based Dendritic Growth via Twinning-Plane Induced Crystallization
	Zhao, Yang 2,3; Ye, Zhaoqi 2,3; Wang, Lei 2,3,6; Zhang, Hongbin 1; Xue, Fangqi 2,3; Xie, Songhai 2,3; Cao, Xiao-Ming 4,5; Zhang, Yahong 2,3; Tang, Yi 2,3
刊名	CRYSTAL GROWTH & DESIGN
	2018-02-01
卷号	18 期号:2 页码:1101-1108
ISSN号	1528-7483
DOI	10.1021/acs.cgd.7b01547
文献子类	Article
英文摘要	Constructing superstructured crystalline :materials by crystal engineering is an attractive objective for miscellaneous fields of researchers spanning biominietics to catalytic materials. Zeolite is a kind of important crystalline catalyst, and superstructured zeolite has great potential for wideSpread applications. However, the ambiguous crystallization mechanisms hamper the effective and scientific fabrication of superstructured zeolite with exceptional properties. Herein, a fractal superstructured MTW zeolite with mesocrystal side branches is prepared via, a nanoparticle-based nonclassical pathway with twinning plane induced crystallization, which is distinct from the formation of general mesocrystal via crystal-crystal oriented attachment. Deformed atomic connection at a specific crystallographic plane contributes to the production of side branches. Moreover, this intriguing morphology could be regulated merely via adjusting the crystallization kinetics based on the unequivocal nonclassical crystallization mechanism. It will open a new avenue for design and synthesis of targeted crystals with superstructure and extraordinary properties.
WOS关键词	HETEROGENEOUS SYSTEM ; ORIENTED ATTACHMENT ; ZSM-12 ZEOLITE ; MECHANISM ; MORPHOLOGY ; TEMPLATES ; EVOLUTION ; DIRECTION ; PATHWAYS ; CRYSTALS
WOS研究方向	Chemistry ; Crystallography ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000424851400066
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168830]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhang, Hongbin; Tang, Yi
作者单位	1.Fudan Univ Lib, Inst Preservat Chinese Ancient Books, Shanghai 200433, Peoples R China 2.Fudan Univ, Collaborat Innovat Ctr Chem Energy Mat, Dept Chem, Lab Adv Mat, Shanghai 200433, Peoples R China 3.Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China 4.East China Univ Sci & Technol, Ctr Computat Chem, Key Lab Adv Mat, Shanghai 200237, Peoples R China 5.East China Univ Sci & Technol, Sch Chem & Mol Engn, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China 6.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Yang,Ye, Zhaoqi,Wang, Lei,et al. Engineering Fractal MTW Zeolite Mesocrystal: Particle-Based Dendritic Growth via Twinning-Plane Induced Crystallization[J]. CRYSTAL GROWTH & DESIGN,2018,18(2):1101-1108.
APA	Zhao, Yang.,Ye, Zhaoqi.,Wang, Lei.,Zhang, Hongbin.,Xue, Fangqi.,...&Tang, Yi.(2018).Engineering Fractal MTW Zeolite Mesocrystal: Particle-Based Dendritic Growth via Twinning-Plane Induced Crystallization.CRYSTAL GROWTH & DESIGN,18(2),1101-1108.
MLA	Zhao, Yang,et al."Engineering Fractal MTW Zeolite Mesocrystal: Particle-Based Dendritic Growth via Twinning-Plane Induced Crystallization".CRYSTAL GROWTH & DESIGN 18.2(2018):1101-1108.