STANDARDIZATION OF DIFFERENT OCTADECYL BONDED PHASES BASED ON THE RETENTION EQUATION IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY

	STANDARDIZATION OF DIFFERENT OCTADECYL BONDED PHASES BASED ON THE RETENTION EQUATION IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY
	CHEN, N; ZHANG, Y; LU, P
刊名	JOURNAL OF LIQUID CHROMATOGRAPHY
	1992
卷号	15 期号:17 页码:3141-3155
ISSN号	0148-3919
文献子类	Article
英文摘要	The method for standardization of different n - octadecyl (C18) bonded phases is discussed based on the retention equation log k' = k(w) + cphi in reversed-phase high-performance liquid chromatography (RP-HPLC). The dependence of log k' on eluent composition results in parallel lines for C18 reversed phases. The difference in C18 bonded phases can be compensated for by using hydrophilic index c which is independent of C18 reversed phases for a particular solute. The difference between C18 columns packed with C18 reversed phases arises from the difference in phase ratio. A linear relationship between parameter k(w) and the logarithm of the surface coverage of C18 bonded phases has been found. Linear k(w) - k(w) plots with unit slope on various column pairs have been demonstrated. k(w) - k(w) plots have been utilized to transfer of retention values from one C18 column to another over a wide range concentration of mobile phase in RP-HPLC.
WOS研究方向	Biochemistry & Molecular Biology ; Chemistry
语种	英语
出版者	MARCEL DEKKER INC
WOS记录号	WOS:A1992KA91700015
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167882]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	CHEN, N
推荐引用方式 GB/T 7714	CHEN, N,ZHANG, Y,LU, P. STANDARDIZATION OF DIFFERENT OCTADECYL BONDED PHASES BASED ON THE RETENTION EQUATION IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY[J]. JOURNAL OF LIQUID CHROMATOGRAPHY,1992,15(17):3141-3155.
APA	CHEN, N,ZHANG, Y,&LU, P.(1992).STANDARDIZATION OF DIFFERENT OCTADECYL BONDED PHASES BASED ON THE RETENTION EQUATION IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY.JOURNAL OF LIQUID CHROMATOGRAPHY,15(17),3141-3155.
MLA	CHEN, N,et al."STANDARDIZATION OF DIFFERENT OCTADECYL BONDED PHASES BASED ON THE RETENTION EQUATION IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY".JOURNAL OF LIQUID CHROMATOGRAPHY 15.17(1992):3141-3155.