Enantioselective palladium-catalyzed C-H functionalization of pyrroles using an axially chiral 2,2 '-bipyridine ligand

doi:10.1039/c7qo00815e

	Enantioselective palladium-catalyzed C-H functionalization of pyrroles using an axially chiral 2,2 '-bipyridine ligand
	Liu, Cong 1; Zhou, Yong-Gui 1; Shen, Hong-Qiang 1,2; Zhou, Ji 1
刊名	ORGANIC CHEMISTRY FRONTIERS
	2018-02-21
卷号	5 期号:4 页码:611-614
ISSN号	2052-4129
DOI	10.1039/c7qo00815e
文献子类	Article
英文摘要	An enantioselective C-H functionalization of pyrrole derivatives with diazo compounds has been successfully realized with up to 90% ee by employing dichlorobis(benzonitrile) palladium with an axially chiral bipyridine ligand C3-ACBP as the catalyst. Asymmetric C-H functionalization at the gram scale was also conducted smoothly with good reactivity and enantioselectivity.
WOS关键词	FRIEDEL-CRAFTS ALKYLATION ; ALPHA-DIAZOCARBONYL COMPOUNDS ; CROSS-COUPLING REACTIONS ; ASYMMETRIC FUNCTIONALIZATION ; DIRHODIUM(II) CARBOXYLATES ; RHODIUM CARBENOIDS ; COPPER-COMPLEXES ; INDOLES ; INSERTION ; BONDS
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000431292400016
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167186]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhou, Yong-Gui
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Cong,Zhou, Yong-Gui,Shen, Hong-Qiang,et al. Enantioselective palladium-catalyzed C-H functionalization of pyrroles using an axially chiral 2,2 '-bipyridine ligand[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(4):611-614.
APA	Liu, Cong,Zhou, Yong-Gui,Shen, Hong-Qiang,&Zhou, Ji.(2018).Enantioselective palladium-catalyzed C-H functionalization of pyrroles using an axially chiral 2,2 '-bipyridine ligand.ORGANIC CHEMISTRY FRONTIERS,5(4),611-614.
MLA	Liu, Cong,et al."Enantioselective palladium-catalyzed C-H functionalization of pyrroles using an axially chiral 2,2 '-bipyridine ligand".ORGANIC CHEMISTRY FRONTIERS 5.4(2018):611-614.