Efficient conversion of 5-hydroxymethylfurfural to high-value chemicals by chemo- and bio-catalysis

doi:10.1039/c8ra05308a

	Efficient conversion of 5-hydroxymethylfurfural to high-value chemicals by chemo- and bio-catalysis
	Xu, Siquan 2,3; Hu, Hong 2,3; An, Jiahuan 2,3; Li, Changzhi 1; Xia, Haian 2,3
刊名	RSC ADVANCES
	2018
卷号	8 期号:54 页码:30875-30886
ISSN号	2046-2069
DOI	10.1039/c8ra05308a
通讯作者	Xia, Haian(haxia@dicp.ac.cn) ; Li, Changzhi(licz@dicp.ac.cn)
英文摘要	5-hydroxymethylfurfural (HMF) is a very important versatile platform compound derived from renewable biomass. The functionalized molecule with an aldehyde group, a hydroxyl group and a furan ring provides great potential for the production of a wide variety of valuable chemicals. This review highlights the latest advances in the catalytic conversion of HMF into value-added chemicals by some important reactions including (1) aerobic oxidation of HMF into furan-based aldehydes and acids such as 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 2,5-diformylfuran (DFF), and furandicarboxylic acid (FDCA), (2) reductive amination of HMF to amine, (3) the synthesis of aromatics by Diels-alder reaction followed by a dehydration reaction, (4) catalytic reduction of HMF into 2,5-bis(hydroxymethyl)furan (BHMF), and 2,5-dimethyl furan (DMF), (5) catalytic oxidation of HMF into maleic anhydride, and some other important transformations. The review mainly focuses on the recent progress in bio-catalytic, electrocatalytic, and heterogeneous catalytic transformation of HMF into high value chemicals over the past few years. Moreover, an outlook is provided to highlight opportunities and challenges related to this hot research topic.
资助项目	National Key R&D Program of China[2017YFD0601006] ; National Key R&D Program of China[2016YFA0202801] ; Natural Science Foundation of Jiangsu province[BK20171452] ; Natural Science Foundation of China[31200445] ; Natural Science Foundation of China[21690080] ; Natural Science Foundation of China[21690083] ; Natural Science Foundation of Jiangsu Higher Education Institutes of China[16KJB220003]
WOS关键词	BIOMASS-DERIVED FURANS ; FREE AEROBIC OXIDATION ; RENEWABLE AROMATIC CHEMICALS ; DIRECT REDUCTIVE AMINATION ; ONE-POT PRODUCTION ; 2,5-FURANDICARBOXYLIC ACID ; DIELS-ALDER ; P-XYLENE ; SELECTIVE PRODUCTION ; LEVULINIC ACID
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000444700500029
资助机构	National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of Jiangsu province ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167014]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Changzhi; Xia, Haian
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Jiangsu Prov Key Lab Chem & Utilizat Agroforest B, Nanjing, Jiangsu, Peoples R China 3.Nanjing Forestry Univ, Sch Chem Engn, Nanjing 210037, Jiangsu, Peoples R China
推荐引用方式 GB/T 7714	Xu, Siquan,Hu, Hong,An, Jiahuan,et al. Efficient conversion of 5-hydroxymethylfurfural to high-value chemicals by chemo- and bio-catalysis[J]. RSC ADVANCES,2018,8(54):30875-30886.
APA	Xu, Siquan,Hu, Hong,An, Jiahuan,Li, Changzhi,&Xia, Haian.(2018).Efficient conversion of 5-hydroxymethylfurfural to high-value chemicals by chemo- and bio-catalysis.RSC ADVANCES,8(54),30875-30886.
MLA	Xu, Siquan,et al."Efficient conversion of 5-hydroxymethylfurfural to high-value chemicals by chemo- and bio-catalysis".RSC ADVANCES 8.54(2018):30875-30886.