Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control

doi:10.1016/S1872-2067(18)63134-1

	Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control
	Zhou, Xukai 1,2; Li, Xingwei 1; Sun, Jiaqiong 1
刊名	CHINESE JOURNAL OF CATALYSIS
	2018-11-01
卷号	39 期号:11 页码:1782-1791
关键词	Rh(III)-catalysis Chemo-selectivity Annulation Substrate control Condition control
ISSN号	0253-9837
DOI	10.1016/S1872-2067(18)63134-1
通讯作者	Li, Xingwei(xwli@dicp.ac.cn)
英文摘要	Rh(III)-catalyzed C-H activation of N-protected anilines and chemo-divergent couplings with acroleins/enones have been realized for synthesis of three classes of heterocycles. The oxidative coupling of N-pyridylaniline afforded dihydroquinolones with the acrolein being a major hydrogen acceptor. When the directing group was replaced by pyrimidyl in the same system, redox-neutral coupling occurred to afford hemiaminal ethers. Oxidative annulation of N-pyridylanilines with enones using AgBF4 oxidant afforded atropisomeric quinolinium salts. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
资助项目	National Nature Science Foundation of China[21525208] ; National Nature Science Foundation of China[21472186] ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
WOS关键词	C-H ACTIVATION ; TRANSFER HYDROGENATION ; BOND ACTIVATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; DIRECT FUNCTIONALIZATION ; QUINOLIZIDINE ALKALOIDS ; NITROGEN-HETEROCYCLES ; ALCOHOL OXIDATION ; RHODIUM CATALYSIS ; DIRECTING GROUP
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000447958500008
资助机构	National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166870]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Xingwei
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Xukai,Li, Xingwei,Sun, Jiaqiong. Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(11):1782-1791.
APA	Zhou, Xukai,Li, Xingwei,&Sun, Jiaqiong.(2018).Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control.CHINESE JOURNAL OF CATALYSIS,39(11),1782-1791.
MLA	Zhou, Xukai,et al."Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control".CHINESE JOURNAL OF CATALYSIS 39.11(2018):1782-1791.