Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity

doi:10.1021/acsami.8b12686

	Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity
	Liu, Jiayi 2,5; Li, Xuning 2; Liu, Biao 3; Zhao, Chunxiao 1,2; Kuang, Zhichong 2,5; Hu, Ruisheng 1; Liu, Bin 4; Ao, Zhimin 3; Wang, Junhu 2
刊名	ACS APPLIED MATERIALS & INTERFACES
	2018-11-07
卷号	10 期号:44 页码:38051-38056
关键词	secondary building units shape-controlled Prussian blue analogue DFT calculation Fenton reaction
ISSN号	1944-8244
DOI	10.1021/acsami.8b12686
通讯作者	Liu, Bin(LiuBin@ntu.edu.sg) ; Ao, Zhimin(zhimin.ao@gdut.edu.cn) ; Wang, Junhu(wangjh@dicp.ac.cn)
英文摘要	Controllable synthesis of metal-organic frameworks with well-defined morphology, composition, and size is of great importance toward understanding their structure-property relationship in various applications. Herein, we demonstrate a general strategy to modulate the relative growth rate of the secondary building units (SBUs) along different crystal facets for the synthesis of Fe-Co, Mn0.5Fe0.5-Co, and Mn-Co Prussian blue analogues (PBAs) with tunable morphologies. The same growth rate of SBUs along the {100}, {110}, and {111} surfaces at 0 degrees C results in the formation of spherical PBA particles, while the lowest growth rate of SBUs along the {100} surface resulting from the highest surface energy with increasing reaction temperature induces the formation of PBA cubes. Fenton reaction was used as the model reaction to probe the structure-catalytic activity relation for the as-synthesized catalysts. The cubic Fe-Co PBA was found to exhibit the best catalytic performance with reaction rate constant 6 times higher than that of the spherical counterpart. Via density functional theory calculations, the abundant enclosed {100} facets in cubic Fe-Co PBA were identified to have the highest surface energy and favor high Fenton reaction activity.
资助项目	National Natural Science Foundation of China[21476232] ; National Natural Science Foundation of China[21607029] ; National Natural Science Foundation of China[21777033] ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics[N-16-07] ; China Ministry of Science and Technology[2016YFA0202804] ; Science and Technology Program of Guangdong Province[2017B020216003] ; Science and Technology Program of Guangzhou City[201707010359] ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology
WOS关键词	PRUSSIAN BLUE ANALOGS ; POROUS COORDINATION POLYMERS ; BISPHENOL-A ; HYDROGEN STORAGE ; CO ; PEROXYMONOSULFATE ; DEGRADATION ; FE ; ACTIVATION ; MECHANISM
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000449887600031
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166722]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Liu, Bin; Ao, Zhimin; Wang, Junhu
作者单位	1.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 3.Guangdong Univ Technol, Sch Environm Sci & Engn, Inst Environm Hlth & Pollut Control, Guangzhou Key Lab Environm Catalysis & Pollut Con, Guangzhou 510006, Guangdong, Peoples R China 4.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Jiayi,Li, Xuning,Liu, Biao,et al. Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(44):38051-38056.
APA	Liu, Jiayi.,Li, Xuning.,Liu, Biao.,Zhao, Chunxiao.,Kuang, Zhichong.,...&Wang, Junhu.(2018).Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity.ACS APPLIED MATERIALS & INTERFACES,10(44),38051-38056.
MLA	Liu, Jiayi,et al."Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity".ACS APPLIED MATERIALS & INTERFACES 10.44(2018):38051-38056.