Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides

doi:10.1039/c8qo00861b

	Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides
	Hu, Panjie 1; Zhang, Ying 1; Liu, Bingxian 1; Li, Xingwei 1,2
刊名	ORGANIC CHEMISTRY FRONTIERS
	2018-11-21
卷号	5 期号:22 页码:3263-3266
ISSN号	2052-4129
DOI	10.1039/c8qo00861b
通讯作者	Liu, Bingxian(liubx1120@163.com) ; Li, Xingwei(xwli@dicp.ac.cn)
英文摘要	Rhodium(iii)-catalyzed regio- and chemoselective [5 + 2] annulation between N-(cyanoacetyl)indolines and sulfoxonium ylides has been realized, leading to efficient construction of seven-membered rings under mild conditions. This reaction proceeded via C-H activation with sulfoxonium ylides as carbene synthons.
资助项目	NSFC[21525208] ; NSFC[21472186] ; Henan Normal University[5101034011009] ; Henan Normal University[qd16111]
WOS关键词	CASCADE OXIDATIVE ANNULATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; BOND FUNCTIONALIZATION ; INTERNAL ALKYNES ; ACTIVATION ; ARENES ; DERIVATIVES ; CYCLIZATION ; CLEAVAGE ; KETONES
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000449412800010
资助机构	NSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166666]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Liu, Bingxian; Li, Xingwei
作者单位	1.Henan Normal Univ, Henan Key Lab Organ Funct Mol & Drug Innovat, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Hu, Panjie,Zhang, Ying,Liu, Bingxian,et al. Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(22):3263-3266.
APA	Hu, Panjie,Zhang, Ying,Liu, Bingxian,&Li, Xingwei.(2018).Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides.ORGANIC CHEMISTRY FRONTIERS,5(22),3263-3266.
MLA	Hu, Panjie,et al."Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides".ORGANIC CHEMISTRY FRONTIERS 5.22(2018):3263-3266.