Noble metal-free upgrading of multi-unsaturated biomass derivatives at room temperature: silyl species enable reactivity

doi:10.1039/c8gc02934b

	Noble metal-free upgrading of multi-unsaturated biomass derivatives at room temperature: silyl species enable reactivity
	Li, Hu 2; Zhao, Wenfeng 2; Dai, Wenshuai 3,4; Long, Jingxuan 2; Watanabe, Masaru 5; Meier, Sebastian 1; Saravanamurugan, Shunmugavel 6; Yang, Song 2; Riisager, Anders 1
刊名	GREEN CHEMISTRY
	2018-12-07
卷号	20 期号:23 页码:5327-5335
ISSN号	1463-9262
DOI	10.1039/c8gc02934b
通讯作者	Meier, Sebastian(semei@kemi.dtu.dk) ; Saravanamurugan, Shunmugavel(saravana@ciab.res.in) ; Yang, Song(jhzx.msm@gmail.com)
英文摘要	Biomass derivatives are a class of oxygen-rich organic compounds, which can be selectively upgraded to various value-added molecules by partial or complete hydrogenation over metal catalysts. Here, we show that Cs2CO3, a low-cost commercial chemical, enables the selective reduction of dicarbonyl compounds including bio-derived carboxides to monohydric esters/amides, hydroxylamines or diols with high yields (82-99%) at room temperature using eco-friendly and equivalent hydrosilane as a hydride donor. The in situ formation of silyl ether enables the developed catalytic system to tolerate other unsaturated groups and permits a wide substrate scope with high selectivities. Spectroscopic and computational studies elucidate reaction pathways with an emphasis on the role of endogenous siloxane.
资助项目	National Natural Science Foundation of China[21576059] ; National Natural Science Foundation of China[21666008] ; Fok Ying-Tong Education Foundation[161030] ; Guizhou Science & Technology Foundation[[2018]1037] ; Guizhou Science & Technology Foundation[[2017]5788] ; Key Technologies R&D Program of China[2014BAD23B01] ; Department of Biotechnology (Government of India) New Delhi, India
WOS关键词	CARBOXYLIC-ACID DERIVATIVES ; LEVULINIC ACID ; GAMMA-VALEROLACTONE ; SELECTIVE HYDROGENATION ; ONE-POT ; CATALYZED HYDROGENATION ; REDUCTIVE AMINATION ; AMIDES ; MILD ; EFFICIENT
WOS研究方向	Chemistry ; Science & Technology - Other Topics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000451658000011
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying-Tong Education Foundation ; Fok Ying-Tong Education Foundation ; Guizhou Science & Technology Foundation ; Guizhou Science & Technology Foundation ; Key Technologies R&D Program of China ; Key Technologies R&D Program of China ; Department of Biotechnology (Government of India) New Delhi, India ; Department of Biotechnology (Government of India) New Delhi, India ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying-Tong Education Foundation ; Fok Ying-Tong Education Foundation ; Guizhou Science & Technology Foundation ; Guizhou Science & Technology Foundation ; Key Technologies R&D Program of China ; Key Technologies R&D Program of China ; Department of Biotechnology (Government of India) New Delhi, India ; Department of Biotechnology (Government of India) New Delhi, India ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying-Tong Education Foundation ; Fok Ying-Tong Education Foundation ; Guizhou Science & Technology Foundation ; Guizhou Science & Technology Foundation ; Key Technologies R&D Program of China ; Key Technologies R&D Program of China ; Department of Biotechnology (Government of India) New Delhi, India ; Department of Biotechnology (Government of India) New Delhi, India ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fok Ying-Tong Education Foundation ; Fok Ying-Tong Education Foundation ; Guizhou Science & Technology Foundation ; Guizhou Science & Technology Foundation ; Key Technologies R&D Program of China ; Key Technologies R&D Program of China ; Department of Biotechnology (Government of India) New Delhi, India ; Department of Biotechnology (Government of India) New Delhi, India
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166596]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Meier, Sebastian; Saravanamurugan, Shunmugavel; Yang, Song
作者单位	1.Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark 2.Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, State Local Joint Engn Lab Comprehens Utilizat Bi, Minist Educ,Ctr R&D Fine Chem,Key Lab Green Pesti, Guiyang 550025, Guizhou, Peoples R China 3.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100049, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Tohoku Univ, Grad Sch Engn, Res Ctr Supercrit Fluid Technol, Aoba Ku, 6-6-11 Aoba, Sendai, Miyagi 9808579, Japan 6.CIAB, Lab Bioprod Chem, Mohali 140306, Punjab, India
推荐引用方式 GB/T 7714	Li, Hu,Zhao, Wenfeng,Dai, Wenshuai,et al. Noble metal-free upgrading of multi-unsaturated biomass derivatives at room temperature: silyl species enable reactivity[J]. GREEN CHEMISTRY,2018,20(23):5327-5335.
APA	Li, Hu.,Zhao, Wenfeng.,Dai, Wenshuai.,Long, Jingxuan.,Watanabe, Masaru.,...&Riisager, Anders.(2018).Noble metal-free upgrading of multi-unsaturated biomass derivatives at room temperature: silyl species enable reactivity.GREEN CHEMISTRY,20(23),5327-5335.
MLA	Li, Hu,et al."Noble metal-free upgrading of multi-unsaturated biomass derivatives at room temperature: silyl species enable reactivity".GREEN CHEMISTRY 20.23(2018):5327-5335.