Growth and structures of monolayer and bilayer CeOx nanostructures on Au (111) | |
Fan, Yang2; Bao Xinhe2; Yi, Zhang1,2 | |
刊名 | SURFACE SCIENCE |
2019 | |
卷号 | 679页码:31-36 |
关键词 | CeOx nanostructures Au(111) Scanning tunneling microscopy Monolayer Bilayer O vacancy |
ISSN号 | 0039-6028 |
DOI | 10.1016/j.susc.2018.08.017 |
通讯作者 | Fan, Yang(fyang@dicp.ac.cn) |
英文摘要 | The construction of well-defined Ceo(x)/Au(111) model catalysts is key to the understanding of ceria-based catalysts or the Au-CeOx interface in catalytic reactions. Conventionally, owing to the Volmer-Weber growth of ceria on Au(111), ceria nanostructures with controlled layer thickness and well-defined structure have been difficult to grow on Au(111). We explored the influence of growth parameters, such as the substrate temperature for ceria deposition, the flux of Ce atoms and the annealing temperature in this study. We found that ceria prefers to form bilayer nanostructures, i.e. two O-Ce-O layers, over a large range of growth conditions, whereas monolayer ceria nanostructures could also be obtained on Au(111) with the careful control of growth kinetics. Upon the growth of these well-defined ceria nanostructures, element-specific STM images could also be achieved on their surfaces, which allow the identification of surface and sub-surface O vacancies on ceria. The construction and atomic-scale characterization of these CeOx/Au(111) model catalysts would facilitate the subsequent studies on their surface chemistry and aid our understanding on the catalysis by ceria nanostructures. |
资助项目 | Ministry of Science and Technology of China[2017YFB0602205] ; Ministry of Science and Technology of China[2016YFA0202803] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020200] ; National Science Foundation of China[21473191] ; National Science Foundation of China[91545204] ; Thousand Talents Program for Young Scientists |
WOS关键词 | FILMS ; CERIA ; NANOPARTICLES |
WOS研究方向 | Chemistry ; Physics |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000455063000006 |
资助机构 | Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; Thousand Talents Program for Young Scientists ; Thousand Talents Program for Young Scientists ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; Thousand Talents Program for Young Scientists ; Thousand Talents Program for Young Scientists ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; Thousand Talents Program for Young Scientists ; Thousand Talents Program for Young Scientists ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; Thousand Talents Program for Young Scientists ; Thousand Talents Program for Young Scientists |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166322] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Fan, Yang |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Fan, Yang,Bao Xinhe,Yi, Zhang. Growth and structures of monolayer and bilayer CeOx nanostructures on Au (111)[J]. SURFACE SCIENCE,2019,679:31-36. |
APA | Fan, Yang,Bao Xinhe,&Yi, Zhang.(2019).Growth and structures of monolayer and bilayer CeOx nanostructures on Au (111).SURFACE SCIENCE,679,31-36. |
MLA | Fan, Yang,et al."Growth and structures of monolayer and bilayer CeOx nanostructures on Au (111)".SURFACE SCIENCE 679(2019):31-36. |
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