The Charge Storage Mechanisms of 2D Cation-Intercalated Manganese Oxide in Different Electrolytes | |
Levi, Mikhael D.3; Bu, Xudong1; Lei, Shulai2; Dou, Qingyun2,4; Ma, Pengjun2; Yan, Xingbin2,7; Lu, Yulan5; Chai, Yinguang6; Liu, Bao2,4; Ji, Hengxing6 | |
刊名 | ADVANCED ENERGY MATERIALS |
2019 | |
卷号 | 9期号:3页码:10 |
关键词 | cation-intercalated manganese oxide charge storage mechanism electrochemical quartz crystal microbalance operando Raman supercapacitors |
ISSN号 | 1614-6832 |
DOI | 10.1002/aenm.201802707 |
通讯作者 | Yan, Xingbin(xbyan@licp.cas.cn) |
英文摘要 | 2D ion-intercalated metal oxides are emerging promising new electrodes for supercapacitors because of their unique layered structure as well as distinctive electronic properties. To facilitate their application, fundamental study of the charge storage mechanism is required. Herein, it is demonstrated that the application of in situ Raman spectroscopy and electrochemical quartz crystal microbalance with dissipation monitoring (EQCM-D), provides a sufficient basis to elucidate the charge storage mechanism in a typical 2D cation-intercalated manganese oxide (Na0.55Mn2O4 center dot 1.5H(2)O, abbreviated as NMO) in neutral and alkaline aqueous electrolytes. The results reveal that in neutral Na2SO4 electrolytes, NMO mainly displays a surface-controlled pseudocapacitive behavior in the low potential region (0-0.8 V), but when the potential is higher than 0.8 V, an intercalation pseudocapacitive behavior becomes dominant. By contrast, NMO shows a battery-like behavior associated with OH- ions in alkaline NaOH electrolyte. This study verifies that the charge storage mechanism of NMO strongly depends on the type of electrolyte, and even in the same electrolyte, different charging behaviors are revealed in different potential ranges which should be carefully taken into account when optimizing the use of the electrode materials in practical energy-storage devices. |
资助项目 | National Nature Science Foundations of China[21573265] ; National Nature Science Foundations of China[21673263] ; National Nature Science Foundations of China[21805292] ; One-Three-Five Strategic Planning of Chinese Academy of Sciences |
WOS关键词 | QUARTZ-CRYSTAL MICROBALANCE ; ELECTROCHEMICAL ENERGY-STORAGE ; UNDERPOTENTIAL DEPOSITION ; MICROPOROUS CARBONS ; IONIC FLUXES ; DOUBLE-LAYER ; MNO2 ; ELECTRODES ; PERFORMANCE ; CONVERSION |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000456215200009 |
资助机构 | National Nature Science Foundations of China ; National Nature Science Foundations of China ; One-Three-Five Strategic Planning of Chinese Academy of Sciences ; One-Three-Five Strategic Planning of Chinese Academy of Sciences ; National Nature Science Foundations of China ; National Nature Science Foundations of China ; One-Three-Five Strategic Planning of Chinese Academy of Sciences ; One-Three-Five Strategic Planning of Chinese Academy of Sciences ; National Nature Science Foundations of China ; National Nature Science Foundations of China ; One-Three-Five Strategic Planning of Chinese Academy of Sciences ; One-Three-Five Strategic Planning of Chinese Academy of Sciences ; National Nature Science Foundations of China ; National Nature Science Foundations of China ; One-Three-Five Strategic Planning of Chinese Academy of Sciences ; One-Three-Five Strategic Planning of Chinese Academy of Sciences |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166276] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Yan, Xingbin |
作者单位 | 1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China 3.Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel 4.Univ Chinese Acad Sci, Ctr Mat Sci & Opoelect Engn, Beijing 100080, Peoples R China 5.Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China 6.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 7.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116000, Peoples R China |
推荐引用方式 GB/T 7714 | Levi, Mikhael D.,Bu, Xudong,Lei, Shulai,et al. The Charge Storage Mechanisms of 2D Cation-Intercalated Manganese Oxide in Different Electrolytes[J]. ADVANCED ENERGY MATERIALS,2019,9(3):10. |
APA | Levi, Mikhael D..,Bu, Xudong.,Lei, Shulai.,Dou, Qingyun.,Ma, Pengjun.,...&Zhang, Qingnuan.(2019).The Charge Storage Mechanisms of 2D Cation-Intercalated Manganese Oxide in Different Electrolytes.ADVANCED ENERGY MATERIALS,9(3),10. |
MLA | Levi, Mikhael D.,et al."The Charge Storage Mechanisms of 2D Cation-Intercalated Manganese Oxide in Different Electrolytes".ADVANCED ENERGY MATERIALS 9.3(2019):10. |
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