Ir-Based Bimetallic Catalysts for Hydrogen Production through Glycerol Aqueous-Phase Reforming

doi:10.3390/catal8120613

	Ir-Based Bimetallic Catalysts for Hydrogen Production through Glycerol Aqueous-Phase Reforming
	Balla, Putrakumar 2; Chavarria-Hernandez, Juan C.1; Ruiz-Gomez, Miguel 3; Tlecuitl-Beristain, Saul 4; Espinosa-Moreno, Francisco 1; Shen, Wenjie 2
刊名	CATALYSTS
	2018-12-01
卷号	8 期号:12 页码:16
关键词	iridium glycerol aqueous-phase reforming hydrogen production
ISSN号	2073-4344
DOI	10.3390/catal8120613
通讯作者	Chavarria-Hernandez, Juan C.(jc.ch@cicy.mx)
英文摘要	Iridium, Iridium-Nickel and Iridium-Copper catalysts were prepared by incipient wetness impregnation and evaluated in the aqueous-phase reforming of glycerol using La2O3 or CeO2 as supports. The catalysts were characterized by N-2 physisorption, XRD, H-2-TPR, XPS, and EDS. The reactions were carried out in a fixed bed reactor feeding a solution of glycerol (10 wt %) in water, at 270 degrees C and 58 bar. All IrNi catalysts showed higher activity than Ir and IrCu, and in general, La2O3 catalysts showed a better performance when compared to CeO2 catalysts. The highest hydrogen production yield was reached by bimetallic IrNi catalysts with over 250 mu mol min(-1) g(cat)(-1) for La2O3 and 150 mu mol min(-1) g(cat)(-1) for CeO2.
资助项目	CONACYT-SENER/SUSTENTABILIDAD ENERGETICA[FSE-2014-01-254667]
WOS关键词	ETHYLENE-GLYCOL ; FOSSIL-FUELS ; IR/CEO2 CATALYSTS ; ETHANOL ; NI ; HYDROCARBONS ; DEPLETION ; METHANOL ; RE ; PERFORMANCE
WOS研究方向	Chemistry
语种	英语
出版者	MDPI
WOS记录号	WOS:000454711500045
资助机构	CONACYT-SENER/SUSTENTABILIDAD ENERGETICA ; CONACYT-SENER/SUSTENTABILIDAD ENERGETICA ; CONACYT-SENER/SUSTENTABILIDAD ENERGETICA ; CONACYT-SENER/SUSTENTABILIDAD ENERGETICA ; CONACYT-SENER/SUSTENTABILIDAD ENERGETICA ; CONACYT-SENER/SUSTENTABILIDAD ENERGETICA ; CONACYT-SENER/SUSTENTABILIDAD ENERGETICA ; CONACYT-SENER/SUSTENTABILIDAD ENERGETICA
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166242]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Chavarria-Hernandez, Juan C.
作者单位	1.Parque Cient & Tecnol Yucatan, Ctr Invest Cient Yucatan, Carretera Sierra Papacal Chuburna Puerto, Merida 97302, Yucatan, Mexico 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhong Shan Rd, Dalian 116023, Peoples R China 3.CONACYT CINVESTAV IPN, CONACYT Dept Fis Aplicada, Merida 97310, Yucatan, Mexico 4.Univ Politecn Tlaxcala, Ingn Biotecnol, Tepeyanco 90180, Tlaxcala, Mexico
推荐引用方式 GB/T 7714	Balla, Putrakumar,Chavarria-Hernandez, Juan C.,Ruiz-Gomez, Miguel,et al. Ir-Based Bimetallic Catalysts for Hydrogen Production through Glycerol Aqueous-Phase Reforming[J]. CATALYSTS,2018,8(12):16.
APA	Balla, Putrakumar,Chavarria-Hernandez, Juan C.,Ruiz-Gomez, Miguel,Tlecuitl-Beristain, Saul,Espinosa-Moreno, Francisco,&Shen, Wenjie.(2018).Ir-Based Bimetallic Catalysts for Hydrogen Production through Glycerol Aqueous-Phase Reforming.CATALYSTS,8(12),16.
MLA	Balla, Putrakumar,et al."Ir-Based Bimetallic Catalysts for Hydrogen Production through Glycerol Aqueous-Phase Reforming".CATALYSTS 8.12(2018):16.