Carbonyl Linked Carbon Nitride Loading Few Layered MoS2 for Boosting Photocatalytic Hydrogen Generation

doi:10.1021/acssuschemeng.8b05117

	Carbonyl Linked Carbon Nitride Loading Few Layered MoS2 for Boosting Photocatalytic Hydrogen Generation
	Kong, Lingqiao 1,2,3,4; Yan, Junqing 1,2,3,4; Liu, Shengzhong Frank 1,2,3,4,5
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2019-01-07
卷号	7 期号:1 页码:1389-1398
关键词	CO-C3N4 MoS2 Photocatalysis Water splitting H-2 generation
ISSN号	2168-0485
DOI	10.1021/acssuschemeng.8b05117
通讯作者	Yan, Junqing(junqingyan@snnu.edu.cn) ; Liu, Shengzhong Frank(szliu@snnu.edu.cn)
英文摘要	Pristine graphitic carbon nitride g-C3N4 materials, as a novel metal-free photocatalyst with moderate activity, have attracted intense interest. However, its fast photogenerated carriers recombination always induces a relative low performance. Herein, we for the first time report one new =C=O group linked g-C3N4 (CO-C3N4) through CO2-assisted thermal polymerization of urea. It is found that the edge =C=O groups work as the photogenerated electrons collection sites and then promote the carriers separation. The visible-light photo-tatalytic hydrogen evolution performance of our synthesized samples shows 1.85 times higher than that of the reference g-C3N4. To get a considerable visible-light driven photocatalytic hydrogen generation, a new few layered MoS2 with a small size (ca. 20 nm) is prepared through a liquid exfoliation and then is loaded onto the CO-C3N4. The optimal MoS2/CO-C3N4 sample gives the photocatalytic hydrogen evolution of 1990 and 1440 mu mol/(gh) under the lambda > 400 and 420 illumination, higher than the reported values in the literature. The sample also shows a considerable excellent photocatalytic activity of 44.3 mu mol/(gh) under LED-600 condition.
资助项目	National Key Research Program of China[2017YFA0204800] ; National Key Research Program of China[2016YFA0202403] ; Natural Science Foundation of China[21603136] ; National Science Basic Research Plan in Shaanxi Province of China[2017JM2007] ; Changjiang Scholar and Innovative Research Team[IRT_14R33] ; 111 Project[B14041] ; Fundamental Research Funds for the Central Universities[GK201602007] ; Fundamental Research Funds for the Central Universities[2018CSLZ011]
WOS关键词	VISIBLE-LIGHT ; ULTRATHIN NANOSHEETS ; H-2 PRODUCTION ; WATER ; EFFICIENT ; EVOLUTION ; SEMICONDUCTORS ; COCATALYST ; POLYMERS
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000455288800146
资助机构	National Key Research Program of China ; National Key Research Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; National Science Basic Research Plan in Shaanxi Province of China ; National Science Basic Research Plan in Shaanxi Province of China ; Changjiang Scholar and Innovative Research Team ; Changjiang Scholar and Innovative Research Team ; 111 Project ; 111 Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Key Research Program of China ; National Key Research Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; National Science Basic Research Plan in Shaanxi Province of China ; National Science Basic Research Plan in Shaanxi Province of China ; Changjiang Scholar and Innovative Research Team ; Changjiang Scholar and Innovative Research Team ; 111 Project ; 111 Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Key Research Program of China ; National Key Research Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; National Science Basic Research Plan in Shaanxi Province of China ; National Science Basic Research Plan in Shaanxi Province of China ; Changjiang Scholar and Innovative Research Team ; Changjiang Scholar and Innovative Research Team ; 111 Project ; 111 Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Key Research Program of China ; National Key Research Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; National Science Basic Research Plan in Shaanxi Province of China ; National Science Basic Research Plan in Shaanxi Province of China ; Changjiang Scholar and Innovative Research Team ; Changjiang Scholar and Innovative Research Team ; 111 Project ; 111 Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166178]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yan, Junqing; Liu, Shengzhong Frank
作者单位	1.Shaanxi Normal Univ, Minist Educ, Key Lab Appl Surface & Colloid Chem, 620 West Changan Ave, Xian 710119, Shaanxi, Peoples R China 2.Shaanxi Normal Univ, Shaanxi Key Lab Adv Energy Devices, 620 West Changan Ave, Xian 710119, Shaanxi, Peoples R China 3.Shaanxi Normal Univ, Shaanxi Engn Lab Adv Energy Technol, 620 West Changan Ave, Xian 710119, Shaanxi, Peoples R China 4.Shaanxi Normal Univ, Sch Mat Sci & Engn, 620 West Changan Ave, Xian 710119, Shaanxi, Peoples R China 5.Chinese Acad Sci, IChEM, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd Dalian, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Kong, Lingqiao,Yan, Junqing,Liu, Shengzhong Frank. Carbonyl Linked Carbon Nitride Loading Few Layered MoS2 for Boosting Photocatalytic Hydrogen Generation[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(1):1389-1398.
APA	Kong, Lingqiao,Yan, Junqing,&Liu, Shengzhong Frank.(2019).Carbonyl Linked Carbon Nitride Loading Few Layered MoS2 for Boosting Photocatalytic Hydrogen Generation.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(1),1389-1398.
MLA	Kong, Lingqiao,et al."Carbonyl Linked Carbon Nitride Loading Few Layered MoS2 for Boosting Photocatalytic Hydrogen Generation".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.1(2019):1389-1398.