Catalytic oxidative desulfurization of model and real diesel over a molybdenum anchored metal-organic framework

doi:10.1016/j.micromeso.2018.11.004

	Catalytic oxidative desulfurization of model and real diesel over a molybdenum anchored metal-organic framework
	Zhang, Jian 1,3; Liu, Ying-Ya 1; Leus, Karen 2; Sun, Zhichao 1; Li, Xiang 1; Depauw, Hannes 2; Wang, Anjie 1; Van der Voort, Pascal 2
刊名	MICROPOROUS AND MESOPOROUS MATERIALS
	2019-03-15
卷号	277 页码:245-252
关键词	Molybdenum-bipyridine complex Metal-organic framework Oxidative desulfurization Dibenzothiophene Diesel
ISSN号	1387-1811
DOI	10.1016/j.micromeso.2018.11.004
通讯作者	Wang, Anjie(ajwang@dlut.edu.cn)
英文摘要	In this work, we report the catalytic performance of a MoO2Cl2 anchored metal-organic framework, Mo@COMOC-4, in the oxidative desulfurization (ODS) process on a continuous fixed-bed reactor. Mo@COMOC-4 was examined as a catalyst in the oxidation of model oils containing dibenzothiophene (DBT), benzothiophene (BT) or 4,6-dimethyldibenzothiophene (4,6-DMDBT). In a 50-h ODS reaction of DBT at 70 degrees C, with tert-butyl hydroperoxide (TBHP) as the oxidant, a constant high DBT conversion of nearly 80% was observed along with a high oxidant utility of over 85%, where DBT was converted rapidly into DBT sulfone. XRD and ICP analysis show that the structure of Mo@COMOC-4 was well preserved, with no significant leaching of Mo species. In addition, Mo@COMOC-4 can also oxidize a hydrogenated diesel oil, and 74% sulfur removal efficiency was achieved, with an extraction recovery of 92.5% after acetonitrile extraction. Spectroscopic characterization confirmed the formation of a molybdenum peroxide complex from MoO2Cl2 under TBHP treatment, a plausible catalytic process was proposed based on the experiment evidence as well as FT-IR and FT-FIR characterization results.
资助项目	International S&T Cooperation Program of China[2016YFE0109800] ; National Natural Science Foundation of China[21403025] ; National Natural Science Foundation of China[21373215] ; National Natural Science Foundation of China[21473017] ; National Natural Science Foundation of China[21603024] ; National Natural Science Foundation of China[21673029] ; National Natural Science Foundation of China[U1162203] ; National Natural Science Foundation of China[U1508205] ; State Key Laboratory of Fine Chemicals[KF1405] ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen)[3G000117]
WOS关键词	LIGHT GAS OIL ; HETEROGENEOUS CATALYSTS ; OXIDE ; BIPYRIDINE ; DIBENZOTHIOPHENES ; IMMOBILIZATION ; PERFORMANCE ; REDUCTION ; COMPLEXES ; FUEL
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000457662500031
资助机构	International S&T Cooperation Program of China ; International S&T Cooperation Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; State Key Laboratory of Fine Chemicals ; State Key Laboratory of Fine Chemicals ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen) ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen) ; International S&T Cooperation Program of China ; International S&T Cooperation Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; State Key Laboratory of Fine Chemicals ; State Key Laboratory of Fine Chemicals ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen) ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen) ; International S&T Cooperation Program of China ; International S&T Cooperation Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; State Key Laboratory of Fine Chemicals ; State Key Laboratory of Fine Chemicals ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen) ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen) ; International S&T Cooperation Program of China ; International S&T Cooperation Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; State Key Laboratory of Fine Chemicals ; State Key Laboratory of Fine Chemicals ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen) ; Research Foundation - Flanders, Belgium (FWO-Vlaanderen)
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166146]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Anjie
作者单位	1.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116029, Peoples R China 2.Univ Ghent, Dept Chem, COMOC, Krijgslaan 281-S3, B-9000 Ghent, Belgium 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Jian,Liu, Ying-Ya,Leus, Karen,et al. Catalytic oxidative desulfurization of model and real diesel over a molybdenum anchored metal-organic framework[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2019,277:245-252.
APA	Zhang, Jian.,Liu, Ying-Ya.,Leus, Karen.,Sun, Zhichao.,Li, Xiang.,...&Van der Voort, Pascal.(2019).Catalytic oxidative desulfurization of model and real diesel over a molybdenum anchored metal-organic framework.MICROPOROUS AND MESOPOROUS MATERIALS,277,245-252.
MLA	Zhang, Jian,et al."Catalytic oxidative desulfurization of model and real diesel over a molybdenum anchored metal-organic framework".MICROPOROUS AND MESOPOROUS MATERIALS 277(2019):245-252.