Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr

doi:10.1016/j.apcata.2018.12.011

	Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr
	Ma, Mingwei 1; Liu, Jinchan 1; Yang, Yongquan 1; Liu, Hui 1; Xu, Xingliang 2; Huang, Jiahui 3; Yue, Huijuan 1; Tian, Ge 1; Feng, Shouhua 1; Cao, Jingjie 1
刊名	APPLIED CATALYSIS A-GENERAL
	2019-02-05
卷号	571 页码:96-101
关键词	Biomass Energy Carbohydrates 5-hydroxymethylfurfural Catalysis
ISSN号	0926-860X
DOI	10.1016/j.apcata.2018.12.011
通讯作者	Tian, Ge(tiange@jlu.edu.cn)
英文摘要	Aluminum ion-exchanged Ca-montmorillonite with different concentrations of aluminum ion were prepared and applied in the conversion of carbohydrates to 5-hydroxymethylfurfural (HMF). It was found that two types of acid sites were present in the catalyst, Lewis acid sites for isomerization of glucose and Bronsted acid sites for dehydration of fructose. With Al-mont-10 as catalyst, the yield of HMF converted from glucose was 80.4% in a biphase system (THF: NaCl solution) at 180 degrees C for 2.5 h. Further, the catalyst also shows excellent catalytic performance in the conversion of starch and inulin, and the yield of HMF reached 60.1% and 81.6% under identical conditions, respectively.
资助项目	National Natural Science Foundation of China[21771086] ; Science and Technology Research Program of the Education Department of Jilin Province, China[JJKH20170778KJ] ; Natural Science Foundation of Jilin Province, China[20180101293JC]
WOS关键词	GLUCOSE CONVERSION ; BETA ZEOLITE ; SN-BETA ; ACID ; DEHYDRATION ; FRUCTOSE ; BIOMASS ; LEWIS ; CLAY ; WATER
WOS研究方向	Chemistry ; Environmental Sciences & Ecology
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000457661200010
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166066]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Tian, Ge
作者单位	1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun, Jilin, Peoples R China 2.Shandong Agr Univ, Coll Chem & Mat Sci, Tai An, Shandong, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Ma, Mingwei,Liu, Jinchan,Yang, Yongquan,et al. Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr[J]. APPLIED CATALYSIS A-GENERAL,2019,571:96-101.
APA	Ma, Mingwei.,Liu, Jinchan.,Yang, Yongquan.,Liu, Hui.,Xu, Xingliang.,...&Cao, Jingjie.(2019).Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr.APPLIED CATALYSIS A-GENERAL,571,96-101.
MLA	Ma, Mingwei,et al."Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr".APPLIED CATALYSIS A-GENERAL 571(2019):96-101.