Application of In Situ Techniques for the Characterization of NiFe-Based Oxygen Evolution Reaction (OER) Electrocatalysts

doi:10.1002/anie.201802923

	Application of In Situ Techniques for the Characterization of NiFe-Based Oxygen Evolution Reaction (OER) Electrocatalysts
	Zhu, Kaiyue 1,2; Yang, Weishen 2; Zhu, Xuefeng 2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2019-01-28
卷号	58 期号:5 页码:1252-1265
关键词	active centers in situ techniques intermediates NiFe-based electrocatalysts oxygen evolution reaction
ISSN号	1433-7851
DOI	10.1002/anie.201802923
通讯作者	Zhu, Xuefeng(zhuxf@dicp.ac.cn) ; Yang, Weishen(yangws@dicp.ac.cn)
英文摘要	Developing high-efficiency and affordable electrocatalysts for the sluggish oxygen evolution reaction (OER) remains a crucial bottleneck on the way to the practical applications of rechargeable energy storage technologies and water splitting for producing clean fuel (H-2). In recent years, NiFe-based materials have proven to be excellent electrocatalysts for OER. Understanding the characteristics that affect OER activity and determining the OER mechanism are of vital importance for the development of OER electrocatalysts. Therefore, in situ characterization techniques performed under OER conditions are urgently needed to monitor the key intermediates together with identifying the OER active centers and phases. In this Minireview, recent advances regarding in situ techniques for the characterization of NiFe-based electrocatalysts are thoroughly summarized, including Raman spectroscopy, X-ray absorption spectroscopy, ambient pressure X-ray photoelectron spectroscopy, Mcssbauer spectroscopy, Ultraviolet-visible spectroscopy, differential electrochemical mass spectrometry, and surface interrogation scanning electrochemical microscopy. The results from these in situ measurements not only reveal the structural transformation and the progressive oxidation of the catalytic species under OER conditions, but also disclose the crucial role of Ni and Fe during the OER. Finally, the need for developing new in situ techniques and theoretical investigations is discussed to better understand the OER mechanism and design promising OER electrocatalysts.
资助项目	National Natural Science Foundation of China[91545202] ; National Natural Science Foundation of China[U1508203] ; National Natural Science Foundation of China[21776267] ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS)[XDB17000000] ; project of Dalian Outstanding Young Scientific and Technical Talents[2016RJ07] ; Youth Innovation Promotion Association of CAS[2014161]
WOS关键词	RAY-ABSORPTION SPECTROSCOPY ; WATER-OXIDATION ; OXYHYDROXIDE ELECTROCATALYSTS ; ELECTROCHEMICAL EVOLUTION ; ELECTRONIC-STRUCTURE ; RAMAN-SPECTROSCOPY ; ENERGY-CONVERSION ; REACTION DYNAMICS ; AIR BATTERIES ; REDOX STATES
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000458826100002
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166006]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yang, Weishen; Zhu, Xuefeng
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Kaiyue,Yang, Weishen,Zhu, Xuefeng. Application of In Situ Techniques for the Characterization of NiFe-Based Oxygen Evolution Reaction (OER) Electrocatalysts[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(5):1252-1265.
APA	Zhu, Kaiyue,Yang, Weishen,&Zhu, Xuefeng.(2019).Application of In Situ Techniques for the Characterization of NiFe-Based Oxygen Evolution Reaction (OER) Electrocatalysts.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(5),1252-1265.
MLA	Zhu, Kaiyue,et al."Application of In Situ Techniques for the Characterization of NiFe-Based Oxygen Evolution Reaction (OER) Electrocatalysts".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.5(2019):1252-1265.